Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 2345-2346 |
| Journal / Publication | Chemical Communications |
| Issue number | 24 |
| Publication status | Published - 1997 |
| Externally published | Yes |
Link(s)
Abstract
Attempted dimethylation of [CpV(NC6H3Pr2i-2,6)]Cl2 using Grignard reagents affords novel μ-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC6H3Pri2-2,6(μ-Me) 2]2(μ-Mg) 2, reveals V-(μ-Me)-Mg, V-Mg, N-Mg and C-H⋯Mg interactions.
Citation Format(s)
Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts. / Chan, Michael C.W.; Cole, Jacqueline M.; Gibson, Vernon C. et al.
In: Chemical Communications, No. 24, 1997, p. 2345-2346.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
