Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au2(dmb)(CN)2 (dmb = 1,8-di-isocyano-p-menthane)
Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal
Author(s)
Detail(s)
Original language | English |
---|---|
Pages (from-to) | 243-244 |
Journal / Publication | Journal of the Chemical Society, Chemical Communications |
Issue number | 4 |
Publication status | Published - 1989 |
Externally published | Yes |
Link(s)
Abstract
Reaction of K[AuCl4] with dmb (1,8-di-isocyano-p-menthane) in boiling ethanol yielded Au2(dmb)(CN)2 with an intramolecular Au-Au separation of 3.536 Å excitation of Au 2(dmb)(CN)2 in fluid solution and in the solid state leads to photoluminescence (λmax. ∼468 nm, τ0 0.13 μs in degassed CH2Cl2).
Citation Format(s)
Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au2(dmb)(CN)2 (dmb = 1,8-di-isocyano-p-menthane). / Che, Chi-Ming; Wong, Wing-Tak; Lai, Ting-Fong et al.
In: Journal of the Chemical Society, Chemical Communications, No. 4, 1989, p. 243-244.
In: Journal of the Chemical Society, Chemical Communications, No. 4, 1989, p. 243-244.
Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal