Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au₂(dmb)(CN)₂ (dmb = 1,8-di-isocyano-p-menthane)

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal

Overview

72 Scopus Citations

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Author(s)

Chi-Ming Che
Wing-Tak Wong
Ting-Fong Lai
Hoi-Lun Kwong

Detail(s)

Original language	English
Pages (from-to)	243-244
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	4
Publication status	Published - 1989
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39890000243 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049069342&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(aa6e6cae-f20d-46a4-968e-cbd8b06d731b).html

Abstract

Reaction of K[AuCl₄] with dmb (1,8-di-isocyano-p-menthane) in boiling ethanol yielded Au₂(dmb)(CN)₂ with an intramolecular Au-Au separation of 3.536 Å excitation of Au ₂(dmb)(CN)₂ in fluid solution and in the solid state leads to photoluminescence (λ_max. ∼468 nm, τ₀ 0.13 μs in degassed CH₂Cl₂).

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Publication fingerprints text

Cyanides Medicine & Life Sciences

Gold Medicine & Life Sciences

Spectrum Analysis Medicine & Life Sciences

Ethanol Medicine & Life Sciences

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Citation Format(s)

[ RIS ] [ BibTeX ]

Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au₂(dmb)(CN)₂ (dmb = 1,8-di-isocyano-p-menthane). / Che, Chi-Ming; Wong, Wing-Tak; Lai, Ting-Fong et al.

In: Journal of the Chemical Society, Chemical Communications, No. 4, 1989, p. 243-244.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal

Che, C-M, Wong, W-T, Lai, T-F & Kwong, H-L 1989, 'Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au₂(dmb)(CN)₂ (dmb = 1,8-di-isocyano-p-menthane)', Journal of the Chemical Society, Chemical Communications, no. 4, pp. 243-244. https://doi.org/10.1039/C39890000243

Che, C-M., Wong, W-T., Lai, T-F., & Kwong, H-L. (1989). Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au₂(dmb)(CN)₂ (dmb = 1,8-di-isocyano-p-menthane). Journal of the Chemical Society, Chemical Communications, (4), 243-244. https://doi.org/10.1039/C39890000243

Che C-M, Wong W-T, Lai T-F, Kwong H-L. Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au₂(dmb)(CN)₂ (dmb = 1,8-di-isocyano-p-menthane). Journal of the Chemical Society, Chemical Communications. 1989;(4):243-244. doi: 10.1039/C39890000243

Che, Chi-Ming ; Wong, Wing-Tak ; Lai, Ting-Fong et al. / Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au₂(dmb)(CN)₂ (dmb = 1,8-di-isocyano-p-menthane). In: Journal of the Chemical Society, Chemical Communications. 1989 ; No. 4. pp. 243-244.