Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato) : Synthesis, structures and magnetic properties

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

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Author(s)

  • Jing Xiang
  • Li-Hui Jia
  • Wai-Lun Man
  • Kang Qian
  • Shek-Man Yiu
  • Gene-Hsiang Lee
  • Shie-Ming Peng
  • Song Gao

Detail(s)

Original languageEnglish
Pages (from-to)8694-8696
Journal / PublicationChemical Communications
Volume47
Issue number30
Publication statusPublished - 14 Aug 2011

Abstract

Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3. © The Royal Society of Chemistry 2011.

Citation Format(s)

Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato) : Synthesis, structures and magnetic properties. / Xiang, Jing; Jia, Li-Hui; Man, Wai-Lun; Qian, Kang; Yiu, Shek-Man; Lee, Gene-Hsiang; Peng, Shie-Ming; Gao, Song; Lau, Tai-Chu.

In: Chemical Communications, Vol. 47, No. 30, 14.08.2011, p. 8694-8696.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal