Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

Jing Xiang; Li-Hui Jia; Wai-Lun Man; Kang Qian; Shek-Man Yiu; Gene-Hsiang Lee; Shie-Ming Peng; Song Gao; Tai-Chu Lau

doi:10.1039/c1cc12446c

Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

Jing Xiang, Li-Hui Jia, Wai-Lun Man, Kang Qian, Shek-Man Yiu, Gene-Hsiang Lee, Shie-Ming Peng, Song Gao, Tai-Chu Lau

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

20 Citations (Scopus)

Abstract

Reaction of [Ru^II(PPh₃)₃Cl₂] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru ^III(Q)₂(CN)₂]^-. It reacts with hydrated CoCl₂ in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3. © The Royal Society of Chemistry 2011.

Original language	English
Pages (from-to)	8694-8696
Journal	Chemical Communications
Volume	47
Issue number	30
DOIs	https://doi.org/10.1039/c1cc12446c
Publication status	Published - 14 Aug 2011

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@article{940cd92440e64c668abedf858f890abf,

title = "Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties",

abstract = "Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3. {\textcopyright} The Royal Society of Chemistry 2011.",

author = "Jing Xiang and Li-Hui Jia and Wai-Lun Man and Kang Qian and Shek-Man Yiu and Gene-Hsiang Lee and Shie-Ming Peng and Song Gao and Tai-Chu Lau",

year = "2011",

month = aug,

day = "14",

doi = "10.1039/c1cc12446c",

language = "English",

volume = "47",

pages = "8694--8696",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

number = "30",

}

Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties. / Xiang, Jing; Jia, Li-Hui; Man, Wai-Lun et al.
In: Chemical Communications, Vol. 47, No. 30, 14.08.2011, p. 8694-8696.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato)

T2 - Synthesis, structures and magnetic properties

AU - Xiang, Jing

AU - Jia, Li-Hui

AU - Man, Wai-Lun

AU - Qian, Kang

AU - Yiu, Shek-Man

AU - Lee, Gene-Hsiang

AU - Peng, Shie-Ming

AU - Gao, Song

AU - Lau, Tai-Chu

PY - 2011/8/14

Y1 - 2011/8/14

N2 - Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3. © The Royal Society of Chemistry 2011.

AB - Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(iii) building block, [Ru III(Q)2(CN)2]-. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3. © The Royal Society of Chemistry 2011.

UR - http://www.scopus.com/inward/record.url?scp=79960553532&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-79960553532&origin=recordpage

U2 - 10.1039/c1cc12446c

DO - 10.1039/c1cc12446c

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 47

SP - 8694

EP - 8696

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -

Novel heterobimetallic ruthenium(iii)-cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]- (Q = 8-quinolinolato): Synthesis, structures and magnetic properties

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