Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)₂C(Me)₂NH}{NH₂C(Me)₂C(Me)₂NH}]ClO₄

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal

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16 Scopus Citations

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Author(s)

Chi-Ming Che
Michael Hon-Wah Lam
Ru-Ji Wang
Thomas C. W. Mak

Detail(s)

Original language	English
Pages (from-to)	820-821
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	11
Publication status	Published - 1990
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39900000820 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049089555&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(05d16ac9-4832-4ce6-a4aa-dd96b6590f4c).html

Abstract

The six-co-ordinate trans-[Os(L)₂(O)₂]²⁺ [L = NH₂C(Me)₂C(Me)₂NH₂] and five-co-ordinate [OsO {NHC(Me)₂C(Me)₂NH} {NH₂C(Me)₂C(Me)₂NH}]⁺ complexes are in equilibrium in solution; the X-ray structure of the five-co-ordinate square pyramidal Os^VI-oxo complex has been determined with a measured Os=O distance of 1.72(2) Å.

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Osmium Medicine & Life Sciences

Ligands Medicine & Life Sciences

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Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)₂C(Me)₂NH}{NH₂C(Me)₂C(Me)₂NH}]ClO₄. / Che, Chi-Ming; Lam, Michael Hon-Wah; Wang, Ru-Ji et al.

In: Journal of the Chemical Society, Chemical Communications, No. 11, 1990, p. 820-821.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal

Che, C-M, Lam, MH-W, Wang, R-J & Mak, TCW 1990, 'Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)₂C(Me)₂NH}{NH₂C(Me)₂C(Me)₂NH}]ClO₄', Journal of the Chemical Society, Chemical Communications, no. 11, pp. 820-821. https://doi.org/10.1039/C39900000820

Che, C-M., Lam, M. H-W., Wang, R-J., & Mak, T. C. W. (1990). Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)₂C(Me)₂NH}{NH₂C(Me)₂C(Me)₂NH}]ClO₄. Journal of the Chemical Society, Chemical Communications, (11), 820-821. https://doi.org/10.1039/C39900000820

Che C-M, Lam MH-W, Wang R-J, Mak TCW. Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)₂C(Me)₂NH}{NH₂C(Me)₂C(Me)₂NH}]ClO₄. Journal of the Chemical Society, Chemical Communications. 1990;(11):820-821. doi: 10.1039/C39900000820

Che, Chi-Ming ; Lam, Michael Hon-Wah ; Wang, Ru-Ji et al. / Novel five-co-ordinate osmium-oxo complex stabilized by diaminato ligands. Synthesis, reactivities, and X-ray crystal structure of [OsO{NHC(Me)₂C(Me)₂NH}{NH₂C(Me)₂C(Me)₂NH}]ClO₄. In: Journal of the Chemical Society, Chemical Communications. 1990 ; No. 11. pp. 820-821.