Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

Michael C.W. Chan; Jacqueline M. Cole; Vernon C. Gibson; Judith A.K. Howard

doi:10.1039/a705256a

Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

Michael C.W. Chan
, Jacqueline M. Cole
, Vernon C. Gibson^*
, Judith A.K. Howard

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

77 Citations (Scopus)

Abstract

Attempted dimethylation of [CpV(NC₆H₃Pr₂ⁱ-2,6)]Cl₂ using Grignard reagents affords novel μ-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC₆H₃Prⁱ₂-2,6(μ-Me)₂]₂(μ-Mg) 2, reveals V-(μ-Me)-Mg, V-Mg, N-Mg and C-H⋯Mg interactions.

Original language	English
Pages (from-to)	2345-2346
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/a705256a
Publication status	Published - 1997
Externally published	Yes

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@article{d200e16d69334776b2e1af3eb2e9ff9a,

title = "Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts",

abstract = "Attempted dimethylation of [CpV(NC6H3Pr2i-2,6)]Cl2 using Grignard reagents affords novel μ-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC6H3Pri2-2,6(μ-Me)2]2(μ-Mg) 2, reveals V-(μ-Me)-Mg, V-Mg, N-Mg and C-H⋯Mg interactions.",

author = "Chan, \{Michael C.W.\} and Cole, \{Jacqueline M.\} and Gibson, \{Vernon C.\} and Howard, \{Judith A.K.\}",

year = "1997",

doi = "10.1039/a705256a",

language = "English",

pages = "2345--2346",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

number = "24",

}

Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts. / Chan, Michael C.W.; Cole, Jacqueline M.; Gibson, Vernon C. et al.
In: Chemical Communications, No. 24, 1997, p. 2345-2346.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

AU - Chan, Michael C.W.

AU - Cole, Jacqueline M.

AU - Gibson, Vernon C.

AU - Howard, Judith A.K.

PY - 1997

Y1 - 1997

N2 - Attempted dimethylation of [CpV(NC6H3Pr2i-2,6)]Cl2 using Grignard reagents affords novel μ-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC6H3Pri2-2,6(μ-Me)2]2(μ-Mg) 2, reveals V-(μ-Me)-Mg, V-Mg, N-Mg and C-H⋯Mg interactions.

AB - Attempted dimethylation of [CpV(NC6H3Pr2i-2,6)]Cl2 using Grignard reagents affords novel μ-methyl complexes arising by reductive dimerisation; the structure of one of these products, [CpV(NC6H3Pri2-2,6(μ-Me)2]2(μ-Mg) 2, reveals V-(μ-Me)-Mg, V-Mg, N-Mg and C-H⋯Mg interactions.

UR - https://www.scopus.com/pages/publications/0000612402

UR - https://www.scopus.com/pages/publications/0000612402#tab=impact

U2 - 10.1039/a705256a

DO - 10.1039/a705256a

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

SP - 2345

EP - 2346

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Novel μ-methyl complexes of vanadium and their relevance to bimolecular deactivation of homogeneous imidovanadium polymerisation catalysts

Abstract

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