Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines

Haiyan Xu; Peng Yang; Pratanphorn Chuanprasit; Hajime Hirao; Jianrong Zhou

doi:10.1002/anie.201501018

Author(s)

Haiyan Xu
Peng Yang
Pratanphorn Chuanprasit
Hajime Hirao
Jianrong Zhou

Detail(s)

Original language	English
Pages (from-to)	5112-5116
Journal / Publication	Angewandte Chemie - International Edition
Volume	54
Issue number	17
Publication status	Published - 20 Apr 2015
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/anie.201501018 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-84927771922&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(9e6b07ad-be94-4446-9f42-d7e2ad1bbb7e).html

Abstract

We report the use of nickel catalysts for the catalytic transfer hydrogenation of hydrazones and other ketimines with formic acid. Strongly donating bisphosphines must be used to support the catalysts. As in enzymatic catalysis, attractive weak interactions may be important for stereochemical control by the nickel/binapine catalyst.

Research Area(s)

asymmetric catalysis, hydrazones, hydride insertion, nickel, transfer hydrogenation

Citation Format(s)

[ RIS ] [ BibTeX ]

Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines. / Xu, Haiyan; Yang, Peng; Chuanprasit, Pratanphorn et al.

In: Angewandte Chemie - International Edition, Vol. 54, No. 17, 20.04.2015, p. 5112-5116.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Xu, H, Yang, P, Chuanprasit, P, Hirao, H & Zhou, J 2015, 'Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines', Angewandte Chemie - International Edition, vol. 54, no. 17, pp. 5112-5116. https://doi.org/10.1002/anie.201501018

Xu, H., Yang, P., Chuanprasit, P., Hirao, H., & Zhou, J. (2015). Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines. Angewandte Chemie - International Edition, 54(17), 5112-5116. https://doi.org/10.1002/anie.201501018

Xu H, Yang P, Chuanprasit P, Hirao H, Zhou J. Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines. Angewandte Chemie - International Edition. 2015 Apr 20;54(17):5112-5116. doi: 10.1002/anie.201501018

Xu, Haiyan ; Yang, Peng ; Chuanprasit, Pratanphorn et al. / Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines. In: Angewandte Chemie - International Edition. 2015 ; Vol. 54, No. 17. pp. 5112-5116.