New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wai-Lun Man; Jing Xiang; Pui-Ha Lau; Song Gao; Wing-Tak Wong; Tai-Chu Lau

doi:10.1007/s11426-010-4119-4

New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Wai-Lun Man
, Jing Xiang
, Pui-Ha Lau
, Song Gao
, Wing-Tak Wong
, Tai-Chu Lau

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

2 Citations (Scopus)

Abstract

A series of tricyanoiron(III) complexes with the general formula mer-[Fe^III(5-Xsap)(CN)₃]^2- (X = H, Me, MeO, Cl or Br, sapH₂ = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh₄)₂[Fe ^III(sap)(CN)₃] and (PPh₄)₂[Fe ^III(5-Mesap)(CN)₃] have been determined by X-ray crystallography. These low-spin d ⁵ tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.

Original language	English
Pages (from-to)	2106-2111
Journal	Science China Chemistry
Volume	53
Issue number	10
DOIs	https://doi.org/10.1007/s11426-010-4119-4
Publication status	Published - Oct 2010

Research Keywords

building block
cyano
iron
molecule-based magnet
Schiff base

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title = "New tricyanoiron(III) building blocks for the construction of molecule-based magnets",

abstract = "A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2- (X = H, Me, MeO, Cl or Br, sapH2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[Fe III(sap)(CN)3] and (PPh4)2[Fe III(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. {\textcopyright} 2010 Science China Press and Springer-Verlag Berlin Heidelberg.",

keywords = "building block, cyano, iron, molecule-based magnet, Schiff base",

author = "Wai-Lun Man and Jing Xiang and Pui-Ha Lau and Song Gao and Wing-Tak Wong and Tai-Chu Lau",

year = "2010",

month = oct,

doi = "10.1007/s11426-010-4119-4",

language = "English",

volume = "53",

pages = "2106--2111",

journal = "Science China Chemistry",

issn = "1674-7291",

publisher = "Springer Nature and Science China Press",

number = "10",

}

TY - JOUR

T1 - New tricyanoiron(III) building blocks for the construction of molecule-based magnets

AU - Man, Wai-Lun

AU - Xiang, Jing

AU - Lau, Pui-Ha

AU - Gao, Song

AU - Wong, Wing-Tak

AU - Lau, Tai-Chu

PY - 2010/10

Y1 - 2010/10

N2 - A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2- (X = H, Me, MeO, Cl or Br, sapH2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[Fe III(sap)(CN)3] and (PPh4)2[Fe III(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.

AB - A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2- (X = H, Me, MeO, Cl or Br, sapH2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[Fe III(sap)(CN)3] and (PPh4)2[Fe III(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.

KW - building block

KW - cyano

KW - iron

KW - molecule-based magnet

KW - Schiff base

UR - https://www.scopus.com/pages/publications/78049458693

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-78049458693&origin=recordpage

U2 - 10.1007/s11426-010-4119-4

DO - 10.1007/s11426-010-4119-4

M3 - RGC 21 - Publication in refereed journal

SN - 1674-7291

VL - 53

SP - 2106

EP - 2111

JO - Science China Chemistry

JF - Science China Chemistry

IS - 10

ER -

New tricyanoiron(III) building blocks for the construction of molecule-based magnets

Abstract

Research Keywords

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