TY - JOUR
T1 - New tricyanoiron(III) building blocks for the construction of molecule-based magnets
AU - Man, Wai-Lun
AU - Xiang, Jing
AU - Lau, Pui-Ha
AU - Gao, Song
AU - Wong, Wing-Tak
AU - Lau, Tai-Chu
PY - 2010/10
Y1 - 2010/10
N2 - A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2- (X = H, Me, MeO, Cl or Br, sapH2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[Fe III(sap)(CN)3] and (PPh4)2[Fe III(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.
AB - A series of tricyanoiron(III) complexes with the general formula mer-[FeIII(5-Xsap)(CN)3]2- (X = H, Me, MeO, Cl or Br, sapH2 = N-salicylidene-o-aminophenol) have been synthesized. These complexes were characterized by IR, ESI-MS, UV/Vis, elemental analysis and magnetic measurements. The structures of (PPh4)2[Fe III(sap)(CN)3] and (PPh4)2[Fe III(5-Mesap)(CN)3] have been determined by X-ray crystallography. These low-spin d 5 tricyanoiron(III) complexes are potential building blocks for the construction of molecule-based magnets. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.
KW - building block
KW - cyano
KW - iron
KW - molecule-based magnet
KW - Schiff base
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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-78049458693&origin=recordpage
U2 - 10.1007/s11426-010-4119-4
DO - 10.1007/s11426-010-4119-4
M3 - RGC 21 - Publication in refereed journal
SN - 1674-7291
VL - 53
SP - 2106
EP - 2111
JO - Science China Chemistry
JF - Science China Chemistry
IS - 10
ER -