New Nanophotonics Approaches for Enhancing the Efficiency and Stability of Perovskite Solar Cells

Over the past decade, the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has experienced a remarkable ascent, soaring from 3.8% in 2009 to a remarkable record of 26.1% in 2023. Many recent approaches for improving PSC performance employ nanophotonic technologies, from light harvesting and thermal management to the manipulation of charge carrier dynamics. Plasmonic nanoparticles and arrayed dielectric nanostructures have been applied to tailor the light absorption, scattering, and conversion, as well as the heat dissipation within PSCs to improve their PCE and operational stability. In this review, it is begin with a concise introduction to define the realm of nanophotonics by focusing on the nanoscale interactions between light and surface plasmons or dielectric photonic structures. Prevailing strategies that utilize resonance-enhanced light–matter interactions for boosting the PCE and stability of PSCs from light trapping, carrier transportation, and thermal management perspectives are then elaborated, and the resultant practical applications, such as semitransparent photovoltaics, colored PSCs, and smart perovskite windows are discussed. Finally, the state-of-the-art nanophotonic paradigms in PSCs are reviewed, and the benefits of these approaches in improving the aesthetic effects and energy-saving character of PSC-integrated buildings are highlighted. © 2024 Wiley-VCH GmbH.