New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties

Qichun Zhang; Peiji Wu; Shuqing Sun; Daoben Zhu; Ming Xong; Zhesheng Ma; Nicheng Shi

doi:10.1016/S0379-6779(98)00152-0

New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties

Qichun Zhang, Peiji Wu, Shuqing Sun, Daoben Zhu^*, Ming Xong, Zhesheng Ma, Nicheng Shi

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

7 Citations (Scopus)

Abstract

The complex HMEDA[Ni(dmit)₂]₂I (HMEDA = Hexamethylethylenediammonium) has been prepared. A single X-ray crystal structure analysis reveals that there are short S ⋯ S contacts between Ni(dmit)₂ dimmers. The monoclinic system, space group p2/n, has cell dimensions: a = 11.710(3) Å, b = 22.559(5) Å, c = 7.374(2) Å, β = 93.000(3)⁰, V = 1945.3(8) Å³, z = 4. Full-matrix least-squares refinement, based on 2989 reflections converged at R = 0.0686. The conductivity of this salt at room temperature is 0.1 S cm^-1 and it shows semiconducting behavior from 20 to 300 K. © 1998 Elsevier Science S.A. All rights reserved.

Original language	English
Pages (from-to)	103-106
Journal	Synthetic Metals
Volume	98
Issue number	2
DOIs	https://doi.org/10.1016/S0379-6779(98)00152-0
Publication status	Published - 4 Dec 1998
Externally published	Yes

Research Keywords

Crystal structure
Dithiolate complexes
Electrical conductivity
Nickel complexes
Synthesis

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@article{f5be84414965422885482c4a3b4f2526,

title = "New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties",

abstract = "The complex HMEDA[Ni(dmit)2]2I (HMEDA = Hexamethylethylenediammonium) has been prepared. A single X-ray crystal structure analysis reveals that there are short S ⋯ S contacts between Ni(dmit)2 dimmers. The monoclinic system, space group p2/n, has cell dimensions: a = 11.710(3) {\AA}, b = 22.559(5) {\AA}, c = 7.374(2) {\AA}, β = 93.000(3)0, V = 1945.3(8) {\AA}3, z = 4. Full-matrix least-squares refinement, based on 2989 reflections converged at R = 0.0686. The conductivity of this salt at room temperature is 0.1 S cm-1 and it shows semiconducting behavior from 20 to 300 K. {\textcopyright} 1998 Elsevier Science S.A. All rights reserved.",

keywords = "Crystal structure, Dithiolate complexes, Electrical conductivity, Nickel complexes, Synthesis, Crystal structure, Dithiolate complexes, Electrical conductivity, Nickel complexes, Synthesis, Crystal structure, Dithiolate complexes, Electrical conductivity, Nickel complexes, Synthesis",

author = "Qichun Zhang and Peiji Wu and Shuqing Sun and Daoben Zhu and Ming Xong and Zhesheng Ma and Nicheng Shi",

year = "1998",

month = dec,

day = "4",

doi = "10.1016/S0379-6779(98)00152-0",

language = "English",

volume = "98",

pages = "103--106",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties

AU - Zhang, Qichun

AU - Wu, Peiji

AU - Sun, Shuqing

AU - Zhu, Daoben

AU - Xong, Ming

AU - Ma, Zhesheng

AU - Shi, Nicheng

PY - 1998/12/4

Y1 - 1998/12/4

N2 - The complex HMEDA[Ni(dmit)2]2I (HMEDA = Hexamethylethylenediammonium) has been prepared. A single X-ray crystal structure analysis reveals that there are short S ⋯ S contacts between Ni(dmit)2 dimmers. The monoclinic system, space group p2/n, has cell dimensions: a = 11.710(3) Å, b = 22.559(5) Å, c = 7.374(2) Å, β = 93.000(3)0, V = 1945.3(8) Å3, z = 4. Full-matrix least-squares refinement, based on 2989 reflections converged at R = 0.0686. The conductivity of this salt at room temperature is 0.1 S cm-1 and it shows semiconducting behavior from 20 to 300 K. © 1998 Elsevier Science S.A. All rights reserved.

AB - The complex HMEDA[Ni(dmit)2]2I (HMEDA = Hexamethylethylenediammonium) has been prepared. A single X-ray crystal structure analysis reveals that there are short S ⋯ S contacts between Ni(dmit)2 dimmers. The monoclinic system, space group p2/n, has cell dimensions: a = 11.710(3) Å, b = 22.559(5) Å, c = 7.374(2) Å, β = 93.000(3)0, V = 1945.3(8) Å3, z = 4. Full-matrix least-squares refinement, based on 2989 reflections converged at R = 0.0686. The conductivity of this salt at room temperature is 0.1 S cm-1 and it shows semiconducting behavior from 20 to 300 K. © 1998 Elsevier Science S.A. All rights reserved.

KW - Crystal structure

KW - Dithiolate complexes

KW - Electrical conductivity

KW - Nickel complexes

KW - Synthesis

KW - Crystal structure

KW - Dithiolate complexes

KW - Electrical conductivity

KW - Nickel complexes

KW - Synthesis

KW - Crystal structure

KW - Dithiolate complexes

KW - Electrical conductivity

KW - Nickel complexes

KW - Synthesis

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0032483842&origin=recordpage

U2 - 10.1016/S0379-6779(98)00152-0

DO - 10.1016/S0379-6779(98)00152-0

M3 - RGC 21 - Publication in refereed journal

SN - 0379-6779

VL - 98

SP - 103

EP - 106

JO - Synthetic Metals

JF - Synthetic Metals

IS - 2

ER -

New bisdithiolene metal complex of the 2-thioxo-1,3-dithiole-4,5-dithiolato(dmit) ligand. Preparation, structure and physical properties

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