Networks of hexagonal hierarchy from a self-similar tritopic molecule

We use the unifying concept of self-similarity to design and construct solid-state networks. The coordination networks reported here feature distinct correlation between the self-similar features of discrete molecules and the hierarchical patterns in infinite networks. We use as the building block a symmetrically backfolded, supertritopic dendrimer, which coordinates with AgSbF ₆, to form complex layered networks that can be dissected as hexagonal hierarchy patterns inherently derived from the self-similar features of the individual molecules. © 2009 American Chemical Society.