Navigating the future of solid oxide fuel cell: Comprehensive insights into fuel electrode related degradation mechanisms and mitigation strategies

Osama Gohar, Muhammad Zubair Khan*, Mohsin Saleem, Ouyang Chun, Zaheer Ud Din Babar, Mian Muneeb Ur Rehman, Amjad Hussain, Kun Zheng, Jung-Hyuk Koh*, Abdul Ghaffar, Iftikhar Hussain, Elena Filonova, Dmitry Medvedev, Martin Motola, Muhammad Bilal Hanif*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

25 Citations (Scopus)

Abstract

Solid Oxide Fuel Cells (SOFCs) have proven to be highly efficient and one of the cleanest electrochemical energy conversion devices. However, the commercialization of this technology is hampered by issues related to electrode performance degradation. This article provides a comprehensive review of the various degradation mechanisms that affect the performance and long-term stability of the SOFC anode caused by the interplay of physical, chemical, and electrochemical processes. In SOFCs, the most used anode material is nickel-yttria stabilized zirconia (Ni–YSZ) due to its advantages of high electronic conductivity and high catalytic activity for H2 fuel. However, various factors affecting the long-term stability of the Ni–YSZ anode, such as redox cycling, carbon coking, sulfur poisoning, and the reduction of the triple phase boundary length due to Ni particle coarsening, are thoroughly investigated. In response, the article summarizes the state-of-the-art diagnostic tools and mitigation strategies aimed at improving the long-term stability of the Ni–YSZ anode. © 2024 Elsevier B.V.
Original languageEnglish
Article number103241
JournalAdvances in Colloid and Interface Science
Volume331
Online published19 Jun 2024
DOIs
Publication statusPublished - Sept 2024

Research Keywords

  • Anode
  • Degradation
  • Ni–YSZ
  • Solid oxide fuel cell
  • Triple phase boundaries

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