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Nature of room-temperature photoluminescence in ZnO

  • W. Shan*
  • , W. Walukiewicz
  • , J. W. Ager III
  • , K. M. Yu
  • , H. B. Yuan
  • , H. P. Xin
  • , G. Cantwell
  • , J. J. Song
  • *Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Abstract

The temperature dependence of the photoluminescence (PL) transitions associated with various excitons and their phonon replicas in high-purity bulk ZnO has been studied at temperatures from 12 K to above room temperature (320 K). Several strong PL emission lines associated with longitudinal optical (LO) phonon replicas of free and bound excitons are clearly observed. The room-temperature PL spectrum is dominated by the phonon replicas of the free exciton transition with the maximum at the first LO phonon replica. The results explain the discrepancy between the transition energy of free exciton determined by reflection measurement and the peak position obtained by the PL measurement. © 2005 American Institute of Physics.
Original languageEnglish
Article number191911
Pages (from-to)1-3
JournalApplied Physics Letters
Volume86
Issue number19
DOIs
Publication statusPublished - 9 May 2005
Externally publishedYes

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