Multiphase-Assembly of Siloxane Oligomers with Improved Mechanical Strength and Water-Enhanced Healing

Meijin Liu, Peng Liu, Gang Lu, Zhengtao Xu, Xi Yao*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

Healable silicone materials have great technical impact in coatings, smart actuators, and flexible electronics, however, current healable silicone materials lack mechanical tunability. Herein, we designed and synthesized a new type of healable silicone through hydrogen-bond assisted multiphase assembly of siloxane oligomers. Besides the enhanced mechanical strength, unique water-enhanced healing was observed in the polymer network which is due to the reversible dissociation/association of multivalent hydrogen bonds in the presence of water.
Original languageEnglish
Pages (from-to)11242–11246
JournalAngewandte Chemie - International Edition
Volume57
Issue number35
Online published11 Jul 2018
DOIs
Publication statusPublished - 27 Aug 2018

Research Keywords

  • Hydrogen bonding
  • Multiphase-assembly
  • Self-healing
  • Siloxane oligomer
  • Supramolecular polymers

RGC Funding Information

  • RGC-funded

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