Multifunctional Spacer in 2D/3D Wide-Bandgap Perovskite for Monolithic Perovskite/Silicon Tandem Solar Cells

Yi-an Ding; Xin Yang; Xiaoting Wang; Yuanzhong Liu; Yiran Yan; Xiangrong Zhu; Jin Huang; Liyou Yang; Lina Li; Qiang Fu; Linfeng Lu; Xiaofei Ji

doi:10.1002/solr.202400189

Multifunctional Spacer in 2D/3D Wide-Bandgap Perovskite for Monolithic Perovskite/Silicon Tandem Solar Cells

Yi-an Ding
, Xin Yang
, Xiaoting Wang
, Yuanzhong Liu
, Yiran Yan
, Xiangrong Zhu
, Jin Huang
, Liyou Yang
, Lina Li
, Qiang Fu^*
, Linfeng Lu^*
, Xiaofei Ji^*

^*Corresponding author for this work

Department of Materials Science and Engineering

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

8 Citations (Scopus)

Abstract

To maximize the power conversion efficiency (PCE) and stability of perovskite/silicon tandem solar cells (TSCs), high-performance and stable perovskite top cells with wide-bandgaps are required. A 2D/3D wide-bandgap perovskite with a bandgap of 1.69 eV using 1H-1,2,4-triazole-1-carboximidamide (1-TzFACl) as a spacer is developed. The 2D/3D wide-bandgap perovskite shows better film quality, enhanced crystallinity, suppressed nonradiative recombination, and significantly improved phase stability. Its initial PCE (21.58%) remains above 87% after 1560 h of continuous illumination due to the insertion of Cl⁻ in the perovskite lattice. A monolithic two-terminal perovskite/silicon TSC achieves a PCE of 25.66% with high light stability. This work provides an ingenious strategy to restrain the phase segregation in wide-bandgap perovskites, leading to effective and stable perovskite/silicon TSCs. © 2024 Wiley-VCH GmbH. © 2024 Wiley-VCH GmbH

Original language	English
Article number	2400189
Journal	Solar RRL
Volume	8
Issue number	11
Online published	7 Apr 2024
DOIs	https://doi.org/10.1002/solr.202400189
Publication status	Published - Jun 2024

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Research Keywords

2D/3D perovskite
defect passivation
perovskite/silicon tandem solar cells
stability
wide-bandgap perovskite

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10.1002/solr.202400189

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title = "Multifunctional Spacer in 2D/3D Wide-Bandgap Perovskite for Monolithic Perovskite/Silicon Tandem Solar Cells",

abstract = "To maximize the power conversion efficiency (PCE) and stability of perovskite/silicon tandem solar cells (TSCs), high-performance and stable perovskite top cells with wide-bandgaps are required. A 2D/3D wide-bandgap perovskite with a bandgap of 1.69 eV using 1H-1,2,4-triazole-1-carboximidamide (1-TzFACl) as a spacer is developed. The 2D/3D wide-bandgap perovskite shows better film quality, enhanced crystallinity, suppressed nonradiative recombination, and significantly improved phase stability. Its initial PCE (21.58\%) remains above 87\% after 1560 h of continuous illumination due to the insertion of Cl− in the perovskite lattice. A monolithic two-terminal perovskite/silicon TSC achieves a PCE of 25.66\% with high light stability. This work provides an ingenious strategy to restrain the phase segregation in wide-bandgap perovskites, leading to effective and stable perovskite/silicon TSCs. {\textcopyright} 2024 Wiley-VCH GmbH. {\textcopyright} 2024 Wiley-VCH GmbH",

keywords = "2D/3D perovskite, defect passivation, perovskite/silicon tandem solar cells, stability, wide-bandgap perovskite",

author = "Yi-an Ding and Xin Yang and Xiaoting Wang and Yuanzhong Liu and Yiran Yan and Xiangrong Zhu and Jin Huang and Liyou Yang and Lina Li and Qiang Fu and Linfeng Lu and Xiaofei Ji",

year = "2024",

month = jun,

doi = "10.1002/solr.202400189",

language = "English",

volume = "8",

number = "11",

}

TY - JOUR

T1 - Multifunctional Spacer in 2D/3D Wide-Bandgap Perovskite for Monolithic Perovskite/Silicon Tandem Solar Cells

AU - Ding, Yi-an

AU - Yang, Xin

AU - Wang, Xiaoting

AU - Liu, Yuanzhong

AU - Yan, Yiran

AU - Zhu, Xiangrong

AU - Huang, Jin

AU - Yang, Liyou

AU - Li, Lina

AU - Fu, Qiang

AU - Lu, Linfeng

AU - Ji, Xiaofei

PY - 2024/6

Y1 - 2024/6

N2 - To maximize the power conversion efficiency (PCE) and stability of perovskite/silicon tandem solar cells (TSCs), high-performance and stable perovskite top cells with wide-bandgaps are required. A 2D/3D wide-bandgap perovskite with a bandgap of 1.69 eV using 1H-1,2,4-triazole-1-carboximidamide (1-TzFACl) as a spacer is developed. The 2D/3D wide-bandgap perovskite shows better film quality, enhanced crystallinity, suppressed nonradiative recombination, and significantly improved phase stability. Its initial PCE (21.58%) remains above 87% after 1560 h of continuous illumination due to the insertion of Cl− in the perovskite lattice. A monolithic two-terminal perovskite/silicon TSC achieves a PCE of 25.66% with high light stability. This work provides an ingenious strategy to restrain the phase segregation in wide-bandgap perovskites, leading to effective and stable perovskite/silicon TSCs. © 2024 Wiley-VCH GmbH. © 2024 Wiley-VCH GmbH

AB - To maximize the power conversion efficiency (PCE) and stability of perovskite/silicon tandem solar cells (TSCs), high-performance and stable perovskite top cells with wide-bandgaps are required. A 2D/3D wide-bandgap perovskite with a bandgap of 1.69 eV using 1H-1,2,4-triazole-1-carboximidamide (1-TzFACl) as a spacer is developed. The 2D/3D wide-bandgap perovskite shows better film quality, enhanced crystallinity, suppressed nonradiative recombination, and significantly improved phase stability. Its initial PCE (21.58%) remains above 87% after 1560 h of continuous illumination due to the insertion of Cl− in the perovskite lattice. A monolithic two-terminal perovskite/silicon TSC achieves a PCE of 25.66% with high light stability. This work provides an ingenious strategy to restrain the phase segregation in wide-bandgap perovskites, leading to effective and stable perovskite/silicon TSCs. © 2024 Wiley-VCH GmbH. © 2024 Wiley-VCH GmbH

KW - 2D/3D perovskite

KW - defect passivation

KW - perovskite/silicon tandem solar cells

KW - stability

KW - wide-bandgap perovskite

UR - https://www.scopus.com/pages/publications/85190370068

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85190370068&origin=recordpage

U2 - 10.1002/solr.202400189

DO - 10.1002/solr.202400189

M3 - RGC 21 - Publication in refereed journal

SN - 2367-198X

VL - 8

JO - Solar RRL

JF - Solar RRL

IS - 11

M1 - 2400189

ER -

Multifunctional Spacer in 2D/3D Wide-Bandgap Perovskite for Monolithic Perovskite/Silicon Tandem Solar Cells

Abstract

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