Multifunctional nitrogen-doped nanoporous carbons derived from metal-organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
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Original language | English |
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Pages (from-to) | 10405-10412 |
Journal / Publication | New Journal of Chemistry |
Volume | 43 |
Issue number | 26 |
Online published | 31 May 2019 |
Publication status | Published - 14 Jul 2019 |
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Abstract
Multifunctional nitrogen-doped nanoporous carbons (N-NPCs) prepared from metal-organic frameworks (MOFs) have been demonstrated. In this work, MOF derived N-NPC possesses a porous structure with a high surface area of 1244 m2 g-1 and well-balanced pore sizes as well as 10% of nitrogen content, which results in good adsorption for CO2 at a medium storage pressure. N-NPC achieved a high CO2 storage capacity of 10 mmol g-1 at 45 bar at 40 °C and still maintained the adsorption of 7.2 mmol g-1 at 100 °C. Due to the short pathway and enhancement of Li ion diffusion, N-NPC exhibited a high initial discharge capacity of 820 mA h g-1 and a reversible charge capacity of 762 mA h g-1 at a rate of 0.1 A g-1. Furthermore, N-NPC reveals a good rate capability, suggesting a potential candidate as an electrode material for Li-ion batteries.
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Multifunctional nitrogen-doped nanoporous carbons derived from metal-organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries. / Shi, Xiaoze; Gong, Jiang; Kierzek, Krzysztof et al.
In: New Journal of Chemistry, Vol. 43, No. 26, 14.07.2019, p. 10405-10412.
In: New Journal of Chemistry, Vol. 43, No. 26, 14.07.2019, p. 10405-10412.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review