TY - JOUR
T1 - Multifunctional nitrogen-doped nanoporous carbons derived from metal-organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries
AU - Shi, Xiaoze
AU - Gong, Jiang
AU - Kierzek, Krzysztof
AU - Michalkiewicz, Beata
AU - Zhang, Shuai
AU - Chu, Paul K.
AU - Chen, Xuecheng
AU - Tang, Tao
AU - Mijowska, Ewa
PY - 2019/7/14
Y1 - 2019/7/14
N2 - Multifunctional nitrogen-doped nanoporous carbons (N-NPCs) prepared from metal-organic frameworks (MOFs) have been demonstrated. In this work, MOF derived N-NPC possesses a porous structure with a high surface area of 1244 m2 g-1 and well-balanced pore sizes as well as 10% of nitrogen content, which results in good adsorption for CO2 at a medium storage pressure. N-NPC achieved a high CO2 storage capacity of 10 mmol g-1 at 45 bar at 40 °C and still maintained the adsorption of 7.2 mmol g-1 at 100 °C. Due to the short pathway and enhancement of Li ion diffusion, N-NPC exhibited a high initial discharge capacity of 820 mA h g-1 and a reversible charge capacity of 762 mA h g-1 at a rate of 0.1 A g-1. Furthermore, N-NPC reveals a good rate capability, suggesting a potential candidate as an electrode material for Li-ion batteries.
AB - Multifunctional nitrogen-doped nanoporous carbons (N-NPCs) prepared from metal-organic frameworks (MOFs) have been demonstrated. In this work, MOF derived N-NPC possesses a porous structure with a high surface area of 1244 m2 g-1 and well-balanced pore sizes as well as 10% of nitrogen content, which results in good adsorption for CO2 at a medium storage pressure. N-NPC achieved a high CO2 storage capacity of 10 mmol g-1 at 45 bar at 40 °C and still maintained the adsorption of 7.2 mmol g-1 at 100 °C. Due to the short pathway and enhancement of Li ion diffusion, N-NPC exhibited a high initial discharge capacity of 820 mA h g-1 and a reversible charge capacity of 762 mA h g-1 at a rate of 0.1 A g-1. Furthermore, N-NPC reveals a good rate capability, suggesting a potential candidate as an electrode material for Li-ion batteries.
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U2 - 10.1039/c9nj01542f
DO - 10.1039/c9nj01542f
M3 - RGC 21 - Publication in refereed journal
SN - 1144-0546
VL - 43
SP - 10405
EP - 10412
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 26
ER -