Multifunctional nitrogen-doped nanoporous carbons derived from metal-organic frameworks for efficient CO2 storage and high-performance lithium-ion batteries

Xiaoze Shi, Jiang Gong, Krzysztof Kierzek, Beata Michalkiewicz, Shuai Zhang, Paul K. Chu, Xuecheng Chen*, Tao Tang*, Ewa Mijowska

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

17 Citations (Scopus)

Abstract

Multifunctional nitrogen-doped nanoporous carbons (N-NPCs) prepared from metal-organic frameworks (MOFs) have been demonstrated. In this work, MOF derived N-NPC possesses a porous structure with a high surface area of 1244 m2 g-1 and well-balanced pore sizes as well as 10% of nitrogen content, which results in good adsorption for CO2 at a medium storage pressure. N-NPC achieved a high CO2 storage capacity of 10 mmol g-1 at 45 bar at 40 °C and still maintained the adsorption of 7.2 mmol g-1 at 100 °C. Due to the short pathway and enhancement of Li ion diffusion, N-NPC exhibited a high initial discharge capacity of 820 mA h g-1 and a reversible charge capacity of 762 mA h g-1 at a rate of 0.1 A g-1. Furthermore, N-NPC reveals a good rate capability, suggesting a potential candidate as an electrode material for Li-ion batteries.
Original languageEnglish
Pages (from-to)10405-10412
JournalNew Journal of Chemistry
Volume43
Issue number26
Online published31 May 2019
DOIs
Publication statusPublished - 14 Jul 2019

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