Molecular Structure of the Ethylenediammonium Complex of a Tetracarboxy‐macrocyclic Receptor Molecule

John J. Daly; Peter Schönholzer; Jean‐Paul Behr; Jean‐Marie Lehn

doi:10.1002/hlca.19810640521

Author(s)

John J. Daly
Peter Schönholzer
Jean‐Paul Behr
Jean‐Marie Lehn

Detail(s)

Original language	English
Pages (from-to)	1444-1451
Journal / Publication	Helvetica Chimica Acta
Volume	64
Issue number	5
Publication status	Published - 22 Jul 1981
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/hlca.19810640521 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0343341479&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(78891530-f71e-41b6-bbd8-6de2119cf82b).html

Abstract

The crystal and molecular structure of the complex formed by the ionized bistartro‐[18]‐crown‐6 receptor molecule 1 with the ethylenediammonium cation, is described. The macrocycle is roughly planar, the carboxy groups of each tartaric acid residue being in a diaxial relationship and extending above and below this plane. This conformation allows ‘lateral’ interactions with bound species to occur. The substrate is sandwiched between two macrocycles, with one of its NH 3+ heads anchored to the polyether core, and the other one in contact with the two carboxy groups of the neighboring molecule. Copyright © 1981 Verlag GmbH & Co. KGaA, Weinheim

Bibliographic Note

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Citation Format(s)

[ RIS ] [ BibTeX ]

Molecular Structure of the Ethylenediammonium Complex of a Tetracarboxy‐macrocyclic Receptor Molecule. / Daly, John J.; Schönholzer, Peter; Behr, Jean‐Paul et al.
In: Helvetica Chimica Acta, Vol. 64, No. 5, 22.07.1981, p. 1444-1451.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Daly, JJ, Schönholzer, P, Behr, JP & Lehn, JM 1981, 'Molecular Structure of the Ethylenediammonium Complex of a Tetracarboxy‐macrocyclic Receptor Molecule', Helvetica Chimica Acta, vol. 64, no. 5, pp. 1444-1451. https://doi.org/10.1002/hlca.19810640521

Daly, J. J., Schönholzer, P., Behr, JP., & Lehn, JM. (1981). Molecular Structure of the Ethylenediammonium Complex of a Tetracarboxy‐macrocyclic Receptor Molecule. Helvetica Chimica Acta, 64(5), 1444-1451. https://doi.org/10.1002/hlca.19810640521

Daly JJ, Schönholzer P, Behr JP, Lehn JM. Molecular Structure of the Ethylenediammonium Complex of a Tetracarboxy‐macrocyclic Receptor Molecule. Helvetica Chimica Acta. 1981 Jul 22;64(5):1444-1451. doi: 10.1002/hlca.19810640521

Daly, John J. ; Schönholzer, Peter ; Behr, Jean‐Paul et al. / Molecular Structure of the Ethylenediammonium Complex of a Tetracarboxy‐macrocyclic Receptor Molecule. In: Helvetica Chimica Acta. 1981 ; Vol. 64, No. 5. pp. 1444-1451.