Modeling the curing kinetics for a modified bismaleimide resin

Freddy Y. C. BOEY; X. L. SONG; C. Y. YUE; Q. ZHAO

doi:10.1002/(SICI)1099-0518(20000301)38:5<907::AID-POLA15>3.0.CO;2-F

Modeling the curing kinetics for a modified bismaleimide resin

Freddy Y. C. BOEY^*, X. L. SONG, C. Y. YUE, Q. ZHAO

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

51 Citations (Scopus)

Abstract

The kinetics of curing for a modified bismaleimide (BMI) has been investigated to ascertain a suitable cure model for the material. The experimental data for characterizing the curing kinetics for a modified bismaleimide resin were determined using a DSC isothermal scan method and indicated a curing mechanism involving multiple reactions. The reaction process was shown to be dominated by a different mechanism at different stages of the cure process, with an initial autocatalytic reaction shifting into an nth order reaction as the reaction proceeded. © 2000 John Wiley & Sons, Inc.

Original language	English
Pages (from-to)	907-913
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	38
Issue number	5
Online published	8 Feb 2000
DOIs	https://doi.org/10.1002/(SICI)1099-0518(20000301)38:5<907::AID-POLA15>3.0.CO;2-F
Publication status	Published - 1 Mar 2000
Externally published	Yes

Research Keywords

bismaleimide
DSC
isothermal curing
curing kinetics
autocatalytic reaction
nth order reaction

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10.1002/(SICI)1099-0518(20000301)38:5<907::AID-POLA15>3.0.CO;2-F

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title = "Modeling the curing kinetics for a modified bismaleimide resin",

abstract = "The kinetics of curing for a modified bismaleimide (BMI) has been investigated to ascertain a suitable cure model for the material. The experimental data for characterizing the curing kinetics for a modified bismaleimide resin were determined using a DSC isothermal scan method and indicated a curing mechanism involving multiple reactions. The reaction process was shown to be dominated by a different mechanism at different stages of the cure process, with an initial autocatalytic reaction shifting into an nth order reaction as the reaction proceeded. {\textcopyright} 2000 John Wiley & Sons, Inc.",

keywords = "bismaleimide, DSC, isothermal curing, curing kinetics, autocatalytic reaction, nth order reaction",

author = "BOEY, {Freddy Y. C.} and SONG, {X. L.} and YUE, {C. Y.} and Q. ZHAO",

year = "2000",

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doi = "10.1002/(SICI)1099-0518(20000301)38:5<907::AID-POLA15>3.0.CO;2-F",

language = "English",

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journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

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TY - JOUR

T1 - Modeling the curing kinetics for a modified bismaleimide resin

AU - BOEY, Freddy Y. C.

AU - SONG, X. L.

AU - YUE, C. Y.

AU - ZHAO, Q.

PY - 2000/3/1

Y1 - 2000/3/1

N2 - The kinetics of curing for a modified bismaleimide (BMI) has been investigated to ascertain a suitable cure model for the material. The experimental data for characterizing the curing kinetics for a modified bismaleimide resin were determined using a DSC isothermal scan method and indicated a curing mechanism involving multiple reactions. The reaction process was shown to be dominated by a different mechanism at different stages of the cure process, with an initial autocatalytic reaction shifting into an nth order reaction as the reaction proceeded. © 2000 John Wiley & Sons, Inc.

AB - The kinetics of curing for a modified bismaleimide (BMI) has been investigated to ascertain a suitable cure model for the material. The experimental data for characterizing the curing kinetics for a modified bismaleimide resin were determined using a DSC isothermal scan method and indicated a curing mechanism involving multiple reactions. The reaction process was shown to be dominated by a different mechanism at different stages of the cure process, with an initial autocatalytic reaction shifting into an nth order reaction as the reaction proceeded. © 2000 John Wiley & Sons, Inc.

KW - bismaleimide

KW - DSC

KW - isothermal curing

KW - curing kinetics

KW - autocatalytic reaction

KW - nth order reaction

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0033875029&origin=recordpage

U2 - 10.1002/(SICI)1099-0518(20000301)38:5<907::AID-POLA15>3.0.CO;2-F

DO - 10.1002/(SICI)1099-0518(20000301)38:5<907::AID-POLA15>3.0.CO;2-F

M3 - RGC 21 - Publication in refereed journal

SN - 0887-624X

VL - 38

SP - 907

EP - 913

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 5

ER -

Modeling the curing kinetics for a modified bismaleimide resin

Abstract

Research Keywords

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