Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+
Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 1883-1884 |
Journal / Publication | Journal of the Chemical Society, Chemical Communications |
Issue number | 24 |
Publication status | Published - 1989 |
Externally published | Yes |
Link(s)
Abstract
UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N2) distances found to be 1.873(9) and 1.893(9) Å.
Citation Format(s)
Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+. / Che, Chi-Ming; Lam, Hon-Wah; Tong, Wai-Fong et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1989, p. 1883-1884.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1989, p. 1883-1884.
Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal