Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+

Chi-Ming Che; Hon-Wah Lam; Wai-Fong Tong; Ting-Fong Lai; Tai-Chu Lau

doi:10.1039/C39890001883

Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os₂(NH₃)₈(MeCN)₂(N₂)]⁵⁺ from [Os^VI(NH₃)₄N]³⁺

Chi-Ming Che, Hon-Wah Lam, Wai-Fong Tong, Ting-Fong Lai, Tai-Chu Lau

Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal

57 Citations (Scopus)

Abstract

UV-VIS irradiation of an acetonitrile solution of [Os^VI(NH₃)₄N](CF₃SO₃)₃ and organic donors under degassed conditions gave [Os₂(NH₃)₈(MeCN)₂(N₂)]⁵⁺; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N₂) distances found to be 1.873(9) and 1.893(9) Å.

Original language	English
Pages (from-to)	1883-1884
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39890001883
Publication status	Published - 1989
Externally published	Yes

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@article{082af583d44f4fb8be0e341c2f0640e1,

title = "Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+",

abstract = "UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N2) distances found to be 1.873(9) and 1.893(9) {\AA}.",

author = "Chi-Ming Che and Hon-Wah Lam and Wai-Fong Tong and Ting-Fong Lai and Tai-Chu Lau",

year = "1989",

doi = "10.1039/C39890001883",

language = "English",

pages = "1883--1884",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "24",

}

Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os₂(NH₃)₈(MeCN)₂(N₂)]⁵⁺ from [Os^VI(NH₃)₄N]³⁺. / Che, Chi-Ming; Lam, Hon-Wah; Tong, Wai-Fong et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1989, p. 1883-1884.

Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal

TY - JOUR

T1 - Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+

AU - Che, Chi-Ming

AU - Lam, Hon-Wah

AU - Tong, Wai-Fong

AU - Lai, Ting-Fong

AU - Lau, Tai-Chu

PY - 1989

Y1 - 1989

N2 - UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N2) distances found to be 1.873(9) and 1.893(9) Å.

AB - UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the μ-dinitrogen complex has been determined and the Os-N(N2) distances found to be 1.873(9) and 1.893(9) Å.

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U2 - 10.1039/C39890001883

DO - 10.1039/C39890001883

M3 - RGC 22 - Publication in policy or professional journal

SN - 0022-4936

SP - 1883

EP - 1884

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -