Mixed-valence CuIICuI15I17 cluster builds up a 3D metal-organic framework with paramagnetic and thermochromic characteristics

Jun He; Jing-Xiang Zhang; Chun-Kwan Tsang; Zhengtao Xu; Ye-Gao Yin; Dan Li; Seik-Weng Ng

doi:10.1021/ic8009207

Author(s)

Jun He
Jing-Xiang Zhang
Chun-Kwan Tsang
Zhengtao Xu
Ye-Gao Yin
And 2 others

Dan Li
Seik-Weng Ng

Detail(s)

Original language	English
Pages (from-to)	7948-7950
Journal / Publication	Inorganic Chemistry
Volume	47
Issue number	18
Publication status	Published - 15 Sep 2008

Link(s)

DOI	DOI https://doi.org/10.1021/ic8009207 Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-52949099818&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(9a811c6d-b4c5-40ad-93ef-6a7d79ee3bcd).html

Abstract

Four cubane-like CU₄I₄ units are assembled around an iodine atom to form the giant, mixed-valent Cu^IICu^I ₁₅I₁₇ cluster. The Cu^IICu^I ₁₅I₁₇ cluster and a bipyrazole linker form a 3D open framework with paramagnetic and thermochromic properties. This paper also touches on the resemblance of this cluster to the self-similar object of a Sierpinski tetrahedron. © 2008 American Chemical Society.

Citation Format(s)

[ RIS ] [ BibTeX ]

Mixed-valence CuIICuI15I17 cluster builds up a 3D metal-organic framework with paramagnetic and thermochromic characteristics. / He, Jun; Zhang, Jing-Xiang; Tsang, Chun-Kwan et al.

In: Inorganic Chemistry, Vol. 47, No. 18, 15.09.2008, p. 7948-7950.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

He, J, Zhang, J-X, Tsang, C-K, Xu, Z, Yin, Y-G, Li, D & Ng, S-W 2008, 'Mixed-valence CuIICuI15I17 cluster builds up a 3D metal-organic framework with paramagnetic and thermochromic characteristics', Inorganic Chemistry, vol. 47, no. 18, pp. 7948-7950. https://doi.org/10.1021/ic8009207

He, J., Zhang, J-X., Tsang, C-K., Xu, Z., Yin, Y-G., Li, D., & Ng, S-W. (2008). Mixed-valence CuIICuI15I17 cluster builds up a 3D metal-organic framework with paramagnetic and thermochromic characteristics. Inorganic Chemistry, 47(18), 7948-7950. https://doi.org/10.1021/ic8009207

He J, Zhang J-X, Tsang C-K, Xu Z, Yin Y-G, Li D et al. Mixed-valence CuIICuI15I17 cluster builds up a 3D metal-organic framework with paramagnetic and thermochromic characteristics. Inorganic Chemistry. 2008 Sep 15;47(18):7948-7950. doi: 10.1021/ic8009207

He, Jun ; Zhang, Jing-Xiang ; Tsang, Chun-Kwan et al. / Mixed-valence CuIICuI15I17 cluster builds up a 3D metal-organic framework with paramagnetic and thermochromic characteristics. In: Inorganic Chemistry. 2008 ; Vol. 47, No. 18. pp. 7948-7950.