Microstructure and mechanical properties of new lead-free Sn-Cu-Re solder alloys

C.M. Lawrence Wu, D. Q. Yu, C. M T Law, L. Wang

    Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

    96 Citations (Scopus)

    Abstract

    The Sn-0.7%Cu alloy has been considered as a lead-free alternative to lead-tin alloys. In this work, various small amounts of rare earth (RE) elements, which are mainly Ce and La, have been added to the Sn-0.7%Cu alloy to form new solder alloys. It was found that the new alloys exhibit mechanical properties superior to that of the Sn-0.7%Cu alloy. In particular, the addition of up to 0.5% of RE elements is found to refine the effective grain size and provide a fine and uniform distribution of Cu6Sn5 in the solidified microstructure. Tensile, creep, and microhardness tests were conducted on the solder alloys. It was found that significant improvements of the tensile strength, microhardness, and creep resistance were obtained with RE element addition. Upon aging at 150°C for 20 h, the microstructure of Sn-Cu-RE is more stable than that of the Sn-Cu alloy.
    Original languageEnglish
    Pages (from-to)928-932
    JournalJournal of Electronic Materials
    Volume31
    Issue number9
    Publication statusPublished - Sept 2002

    Research Keywords

    • Aging
    • Ce and La rare earth elements
    • Creep
    • Tensile strength
    • Tin-copper lead-free alloy

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