Metal–Organic Frameworks Derived Carbon-Supported Metal Electrocatalysts for Energy-Related Reduction Reactions

Jiawei Zhu; Xue Feng Lu; Deyan Luan; Xiong Wen (David) Lou

doi:10.1002/anie.202408846

Author(s)

Jiawei Zhu
Xue Feng Lu
Deyan Luan
Xiong Wen (David) Lou

Related Research Unit(s)

Detail(s)

Original language	English
Article number	e202408846
Journal / Publication	Angewandte Chemie International Edition
Volume	63
Issue number	38
Online published	20 Jun 2024
Publication status	Published - 16 Sept 2024

Link(s)

DOI	DOI https://doi.org/10.1002/anie.202408846 Final Published version
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Attachment(s)	Documents 228769936.pdf Final Published version, 17.3 MB, PDF Publisher's Copyright Statement This full text is made available under CC-BY-NC 4.0. https://creativecommons.org/licenses/by-nc/4.0/
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-85199064602&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(4d581836-9f36-448a-a411-be0b2bf6dfd7).html

Abstract

Electrochemical reduction reactions, as cathodic processes in many energy-related devices, significantly impact the overall efficiency determined mainly by the performance of electrocatalysts. Metal–organic frameworks (MOFs) derived carbon-supported metal materials have become one of star electrocatalysts due to their tunable structure and composition through ligand design and metal screening. However, for different electroreduction reactions, the required active metal species vary in phase component, electronic state, and catalytic center configuration, hence requiring effective customization. From this perspective, this review comprehensively analyzes the structural design principles, metal loading strategies, practical electroreduction performance, and complex catalytic mechanisms, thereby providing insights and guidance for the future rational design of such electroreduction catalysts. © 2024 The Author(s). Angewandte Chemie International Edition published by Wiley-VCH GmbH.