Abstract
Electrochemical reduction reactions, as cathodic processes in many energy-related devices, significantly impact the overall efficiency determined mainly by the performance of electrocatalysts. Metal–organic frameworks (MOFs) derived carbon-supported metal materials have become one of star electrocatalysts due to their tunable structure and composition through ligand design and metal screening. However, for different electroreduction reactions, the required active metal species vary in phase component, electronic state, and catalytic center configuration, hence requiring effective customization. From this perspective, this review comprehensively analyzes the structural design principles, metal loading strategies, practical electroreduction performance, and complex catalytic mechanisms, thereby providing insights and guidance for the future rational design of such electroreduction catalysts. © 2024 The Author(s). Angewandte Chemie International Edition published by Wiley-VCH GmbH.
| Original language | English |
|---|---|
| Article number | e202408846 |
| Journal | Angewandte Chemie International Edition |
| Volume | 63 |
| Issue number | 38 |
| Online published | 20 Jun 2024 |
| DOIs | |
| Publication status | Published - 16 Sept 2024 |
Research Keywords
- carbon supports
- electroreduction
- metal electrocatalysts
- Metal–organic frameworks
Publisher's Copyright Statement
- This full text is made available under CC-BY-NC 4.0. https://creativecommons.org/licenses/by-nc/4.0/