Metal nitrido and imido photo-oxidants. Photophysics and photochemistry of nitrido and imido complexes of osmium(VI) and X-ray crystal structure of [Ph4As]2[OsVI(CN)5N]

Research output: Journal Publications and ReviewsRGC 22 - Publication in policy or professional journal

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Author(s)

  • Chi-Ming Che
  • Michael Hon-Wah Lam
  • Thomas C. W. Mak

Detail(s)

Original languageEnglish
Pages (from-to)1529-1531
Journal / PublicationJournal of the Chemical Society, Chemical Communications
Issue number20
Publication statusPublished - 1989
Externally publishedYes

Abstract

Nitrido- and imido-osmium(VI) complexes with cyanides as ligands have been synthesised and found to display intense photoluminescence in fluid solutions at room temperature; the X-ray structure of [Ph4As]2[Os VI(CN)5N] has been determined with a measured Os≡N distance of 1.647(7) Å.

Citation Format(s)

Metal nitrido and imido photo-oxidants. Photophysics and photochemistry of nitrido and imido complexes of osmium(VI) and X-ray crystal structure of [Ph4As]2[OsVI(CN)5N]. / Che, Chi-Ming; Lam, Michael Hon-Wah; Mak, Thomas C. W.
In: Journal of the Chemical Society, Chemical Communications, No. 20, 1989, p. 1529-1531.

Research output: Journal Publications and ReviewsRGC 22 - Publication in policy or professional journal