Metal nitrido and imido photo-oxidants. Photophysics and photochemistry of nitrido and imido complexes of osmium(VI) and X-ray crystal structure of [Ph4As]2[OsVI(CN)5N]
Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 1529-1531 |
Journal / Publication | Journal of the Chemical Society, Chemical Communications |
Issue number | 20 |
Publication status | Published - 1989 |
Externally published | Yes |
Link(s)
Abstract
Nitrido- and imido-osmium(VI) complexes with cyanides as ligands have been synthesised and found to display intense photoluminescence in fluid solutions at room temperature; the X-ray structure of [Ph4As]2[Os VI(CN)5N] has been determined with a measured Os≡N distance of 1.647(7) Å.
Citation Format(s)
Metal nitrido and imido photo-oxidants. Photophysics and photochemistry of nitrido and imido complexes of osmium(VI) and X-ray crystal structure of [Ph4As]2[OsVI(CN)5N]. / Che, Chi-Ming; Lam, Michael Hon-Wah; Mak, Thomas C. W.
In: Journal of the Chemical Society, Chemical Communications, No. 20, 1989, p. 1529-1531.
In: Journal of the Chemical Society, Chemical Communications, No. 20, 1989, p. 1529-1531.
Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal