Metal-free HB(C6F5)2-catalyzed hydrogenation of unfunctionalized olefins and mechanism study of borane-mediated σ-bond metathesis

Yuwen Wang; Weiqiang Chen; Zhenpin Lu; Zhen Hua Li; Huadong Wang

doi:10.1002/anie.201303500

Metal-free HB(C₆F₅)₂-catalyzed hydrogenation of unfunctionalized olefins and mechanism study of borane-mediated σ-bond metathesis

Yuwen Wang
, Weiqiang Chen
, Zhenpin Lu
, Zhen Hua Li
, Huadong Wang

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

85 Citations (Scopus)

Abstract

Out with the metal: Metal-free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane-mediated σ-bond metathesis, which has been investigated both experimentally and theoretically. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	7496-7499
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	29
DOIs	https://doi.org/10.1002/anie.201303500
Publication status	Published - 15 Jul 2013
Externally published	Yes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

alkenes
boron
hydrogenation
metathesis
synthetic methods

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10.1002/anie.201303500

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Cite this

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title = "Metal-free HB(C6F5)2-catalyzed hydrogenation of unfunctionalized olefins and mechanism study of borane-mediated σ-bond metathesis",

abstract = "Out with the metal: Metal-free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane-mediated σ-bond metathesis, which has been investigated both experimentally and theoretically. Copyright {\textcopyright} 2013 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

keywords = "alkenes, boron, hydrogenation, metathesis, synthetic methods",

author = "Yuwen Wang and Weiqiang Chen and Zhenpin Lu and Li, \{Zhen Hua\} and Huadong Wang",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected]. ",

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volume = "52",

pages = "7496--7499",

journal = "Angewandte Chemie - International Edition",

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Metal-free HB(C₆F₅)₂-catalyzed hydrogenation of unfunctionalized olefins and mechanism study of borane-mediated σ-bond metathesis. / Wang, Yuwen; Chen, Weiqiang; Lu, Zhenpin et al.
In: Angewandte Chemie - International Edition, Vol. 52, No. 29, 15.07.2013, p. 7496-7499.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Metal-free HB(C6F5)2-catalyzed hydrogenation of unfunctionalized olefins and mechanism study of borane-mediated σ-bond metathesis

AU - Wang, Yuwen

AU - Chen, Weiqiang

AU - Lu, Zhenpin

AU - Li, Zhen Hua

AU - Wang, Huadong

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2013/7/15

Y1 - 2013/7/15

N2 - Out with the metal: Metal-free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane-mediated σ-bond metathesis, which has been investigated both experimentally and theoretically. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Out with the metal: Metal-free hydrogenation of unfunctionalized olefins can be achieved by employing HB(C6F5)2 as the catalyst. The key step in the catalytic reaction is believed to involve a novel borane-mediated σ-bond metathesis, which has been investigated both experimentally and theoretically. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - alkenes

KW - boron

KW - hydrogenation

KW - metathesis

KW - synthetic methods

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DO - 10.1002/anie.201303500

M3 - RGC 21 - Publication in refereed journal

SN - 1433-7851

VL - 52

SP - 7496

EP - 7499

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -