Low-temperature methane chlorination with aqueous platinum chlorides in the presence of chlorine

István T. Horváth; Raymond A. Cook; John M. Millar; Gábor Kiss

doi:10.1021/om00025a004

Low-temperature methane chlorination with aqueous platinum chlorides in the presence of chlorine

István T. Horváth, Raymond A. Cook, John M. Millar, Gábor Kiss

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

60 Citations (Scopus)

Abstract

The reaction of methane with chlorine in water at 125°C in the presence of platinum chlorides results in the platinum-assisted formation of methyl chloride which is partially hydrolyzed in situ to methanol. Aqueous Na₂-[PtCl₄] reacts with chlorine at room temperature, resulting in Na₂[PtCl₆], which is the major species in solution even at 125°C. © 1993 American Chemical Society.

Original language	English
Pages (from-to)	8-10
Journal	Organometallics
Volume	12
Issue number	1
DOIs	https://doi.org/10.1021/om00025a004
Publication status	Published - 1993
Externally published	Yes

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title = "Low-temperature methane chlorination with aqueous platinum chlorides in the presence of chlorine",

abstract = "The reaction of methane with chlorine in water at 125°C in the presence of platinum chlorides results in the platinum-assisted formation of methyl chloride which is partially hydrolyzed in situ to methanol. Aqueous Na2-[PtCl4] reacts with chlorine at room temperature, resulting in Na2[PtCl6], which is the major species in solution even at 125°C. {\textcopyright} 1993 American Chemical Society.",

author = "Horv{\'a}th, {Istv{\'a}n T.} and Cook, {Raymond A.} and Millar, {John M.} and G{\'a}bor Kiss",

year = "1993",

doi = "10.1021/om00025a004",

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T1 - Low-temperature methane chlorination with aqueous platinum chlorides in the presence of chlorine

AU - Horváth, István T.

AU - Cook, Raymond A.

AU - Millar, John M.

AU - Kiss, Gábor

PY - 1993

Y1 - 1993

N2 - The reaction of methane with chlorine in water at 125°C in the presence of platinum chlorides results in the platinum-assisted formation of methyl chloride which is partially hydrolyzed in situ to methanol. Aqueous Na2-[PtCl4] reacts with chlorine at room temperature, resulting in Na2[PtCl6], which is the major species in solution even at 125°C. © 1993 American Chemical Society.

AB - The reaction of methane with chlorine in water at 125°C in the presence of platinum chlorides results in the platinum-assisted formation of methyl chloride which is partially hydrolyzed in situ to methanol. Aqueous Na2-[PtCl4] reacts with chlorine at room temperature, resulting in Na2[PtCl6], which is the major species in solution even at 125°C. © 1993 American Chemical Society.

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U2 - 10.1021/om00025a004

DO - 10.1021/om00025a004

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 12

SP - 8

EP - 10

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Low-temperature methane chlorination with aqueous platinum chlorides in the presence of chlorine

Abstract

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