TY - JOUR
T1 - Long-chain alkylammonium organic–inorganic hybrid perovskite for high performance rechargeable aluminon-ion battery
AU - Wu, Shu-Chi
AU - Lai, Zhengxun
AU - Dong, Ruoting
AU - Tang, Shin-Yi
AU - Wang, Kuangye
AU - Yang, Tzu-Yi
AU - Shen, Ying-Chun
AU - Liao, Hsiang-Ju
AU - Su, Teng-Yu
AU - Cheng, Chiou-Ru
AU - Ai, Yuanfei
AU - Chen, Yu-Ze
AU - Wang, Yi-Chung
AU - Lee, Ling
AU - Yu, Yi-Jen
AU - Ho, Johnny C.
AU - Chueh, Yu-Lun
PY - 2023/6/1
Y1 - 2023/6/1
N2 - Recent advances in the use of organic-inorganic hybrid perovskites have been investigated in a variety of applications, such as solar cells, photodetectors, light-emitting devices, and lasers, because of their outstanding semiconductor properties. Furthermore, the perovskite structure can host extrinsic elements, making it a promising candidate for battery applications. Previous studies have shown that organic-inorganic hybrid perovskites can be suitable anode materials for both lithium- and sodium-ion batteries. However, multivalent rechargeable batteries with perovskite materials have not yet been realized. Herein, we studied the electrochemical performance of three-dimensional (CH3NH3PbI3 (MAPbI3) and long-chain alkylammonium (C4H9NH3)2(CH3NH3)3Pb4I13 ((iBA)2(MA)3Pb4I13) thin films as electrode materials for rechargeable Al-ion batteries. Our results showed that (iBA)2(MA)3Pb4I13 presented a specific capacity of 257 mAh g–1 at a current density of 0.1 A g−1 and delivered 108 mAh g–1 after 250 cycles at a current density of 0.3 A g−1 with a retention of as high as 91 %, demonstrating a crucial role of isobutyl amine (C4H9NH3) due to the unique hydrogen-bonding interaction of isobutyl amine that hinders the shuttle effect of polyiodide. The results open a new direction for the use of organic–inorganic hybrid perovskites for new secondary aluminum ion batteries. © 2023 Elsevier Ltd
AB - Recent advances in the use of organic-inorganic hybrid perovskites have been investigated in a variety of applications, such as solar cells, photodetectors, light-emitting devices, and lasers, because of their outstanding semiconductor properties. Furthermore, the perovskite structure can host extrinsic elements, making it a promising candidate for battery applications. Previous studies have shown that organic-inorganic hybrid perovskites can be suitable anode materials for both lithium- and sodium-ion batteries. However, multivalent rechargeable batteries with perovskite materials have not yet been realized. Herein, we studied the electrochemical performance of three-dimensional (CH3NH3PbI3 (MAPbI3) and long-chain alkylammonium (C4H9NH3)2(CH3NH3)3Pb4I13 ((iBA)2(MA)3Pb4I13) thin films as electrode materials for rechargeable Al-ion batteries. Our results showed that (iBA)2(MA)3Pb4I13 presented a specific capacity of 257 mAh g–1 at a current density of 0.1 A g−1 and delivered 108 mAh g–1 after 250 cycles at a current density of 0.3 A g−1 with a retention of as high as 91 %, demonstrating a crucial role of isobutyl amine (C4H9NH3) due to the unique hydrogen-bonding interaction of isobutyl amine that hinders the shuttle effect of polyiodide. The results open a new direction for the use of organic–inorganic hybrid perovskites for new secondary aluminum ion batteries. © 2023 Elsevier Ltd
KW - Aluminum-ion battery
KW - Ionic liquid
KW - Organic–inorganic hybrid perovskites
KW - Polyiodide
KW - Shuttle effect
UR - http://www.scopus.com/inward/record.url?scp=85150861755&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85150861755&origin=recordpage
U2 - 10.1016/j.nanoen.2023.108273
DO - 10.1016/j.nanoen.2023.108273
M3 - RGC 21 - Publication in refereed journal
SN - 2211-2855
VL - 110
JO - Nano Energy
JF - Nano Energy
M1 - 108273
ER -
