Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6

Fei Han; Lei Hu; Zhanning Liu; Qiang Li; Tao Wang; Yang Ren; Jinxia Deng; Jun Chen; Xianran Xing

doi:10.1039/c6qi00483k

Local structure and controllable thermal expansion in the solid solution (Mn_1-xNi_x)ZrF₆

Fei Han, Lei Hu, Zhanning Liu, Qiang Li, Tao Wang, Yang Ren, Jinxia Deng, Jun Chen^*, Xianran Xing

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

12 Citations (Scopus)

Abstract

It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO₃-type (Mn_1-xNi_x)ZrF₆ solid solutions, whose CTE varies from -4.4 to +15.5 × 10^-6 K^-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn_0.6Ni_0.4)ZrF₆. (Mn_1-xNi_x)ZrF₆ exhibits full solid solution character. The thermal expansion of (Mn_1-xNi_x)ZrF₆ is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

Original language	English
Pages (from-to)	343-347
Journal	Inorganic Chemistry Frontiers
Volume	4
Issue number	2
DOIs	https://doi.org/10.1039/c6qi00483k
Publication status	Published - 1 Feb 2017
Externally published	Yes

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title = "Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6",

abstract = "It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 × 10-6 K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix)ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.",

author = "Fei Han and Lei Hu and Zhanning Liu and Qiang Li and Tao Wang and Yang Ren and Jinxia Deng and Jun Chen and Xianran Xing",

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T1 - Local structure and controllable thermal expansion in the solid solution (Mn1-xNix)ZrF6

AU - Han, Fei

AU - Hu, Lei

AU - Liu, Zhanning

AU - Li, Qiang

AU - Wang, Tao

AU - Ren, Yang

AU - Deng, Jinxia

AU - Chen, Jun

AU - Xing, Xianran

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2017/2/1

Y1 - 2017/2/1

N2 - It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 × 10-6 K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix)ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

AB - It is an interesting but challenge issue to prepare isotropic controllable thermal expansion materials with a wide coefficient of thermal expansion (CTE) range. Herein we report controllable thermal expansion in the double ReO3-type (Mn1-xNix)ZrF6 solid solutions, whose CTE varies from -4.4 to +15.5 × 10-6 K-1 (300-700 K). In particular, zero thermal expansion has been obtained in the composition of (Mn0.6Ni0.4)ZrF6. (Mn1-xNix)ZrF6 exhibits full solid solution character. The thermal expansion of (Mn1-xNix)ZrF6 is adjusted by the flexibility of the atomic linkages, which is confirmed by the technique of temperature-dependent high-energy synchrotron X-ray pair distribution function.

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DO - 10.1039/c6qi00483k

M3 - RGC 21 - Publication in refereed journal

SN - 2052-1553

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EP - 347

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

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