Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries

Qing Ai; Qiyi Fang; Jia Liang; Xinyu Xu; Tianshu Zhai; Guanhui Gao; Hua Guo; Guifang Han; Lijie Ci; Jun Lou

doi:10.1016/j.nanoen.2020.104657

Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries

Qing Ai (Co-first Author), Qiyi Fang (Co-first Author), Jia Liang, Xinyu Xu, Tianshu Zhai, Guanhui Gao, Hua Guo, Guifang Han, Lijie Ci^*, Jun Lou^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

132 Citations (Scopus)

Abstract

In this paper, we employ lithium-conducting covalent-organic-framework (COF) as the coating layer for silicon (Si) nanoparticles, which serve as artificial solid electrolyte interphase (SEI) for Si electrode. The COF coating layer reduces the electrolyte decomposition, thus the coulombic efficiency (CE) and cycling stability of the Si electrodes are dramatically improved. Additionally, the superior lithium–ion conductivity of COF can enhance the lithium-ion transportation kinetics of Si electrode. COF coated Si presented a high specific capacity of 1864 mAh g⁻¹ at a high current density of 2000 mA g⁻¹ and high capacity retention of more than 60% after 1000 cycles.

© 2020 Published by Elsevier Ltd.

Original language	English
Article number	104657
Number of pages	7
Journal	Nano Energy
Volume	72
Online published	3 Mar 2020
DOIs	https://doi.org/10.1016/j.nanoen.2020.104657
Publication status	Published - Jun 2020
Externally published	Yes

Funding

Q. Ai, Q. Fang, J. Liang, X. Xu, T. Zhai, H. Guo, J. Lou gratefully acknowledge the financial support by the ARL Cooperative Agreement W911NF-18-2-0062 for COF synthesis, and the Welch foundation grant C-1716 and Department of Energy EERE-VTO Contract DE-EE0008864 for materials characterization. We thank Dr. Ming Tang and Fan Wang at Rice University for their support on electrochemical measurements. We also thank Yifeng Liu and Bo Chen for their support to the Brunauer–Emmett–Teller test. This work was conducted in part using resources of the Shared Equipment Authority at Rice University.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Research Keywords

Artificial solid electrolyte interphase
Covalent-organic-frameworks
Lithium-ion batteries
Si anode

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10.1016/j.nanoen.2020.104657

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@article{7ddc9af36c30439399b6e571e5a0b191,

title = "Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries",

abstract = "In this paper, we employ lithium-conducting covalent-organic-framework (COF) as the coating layer for silicon (Si) nanoparticles, which serve as artificial solid electrolyte interphase (SEI) for Si electrode. The COF coating layer reduces the electrolyte decomposition, thus the coulombic efficiency (CE) and cycling stability of the Si electrodes are dramatically improved. Additionally, the superior lithium–ion conductivity of COF can enhance the lithium-ion transportation kinetics of Si electrode. COF coated Si presented a high specific capacity of 1864 mAh g−1 at a high current density of 2000 mA g−1 and high capacity retention of more than 60% after 1000 cycles. {\textcopyright} 2020 Published by Elsevier Ltd.",

keywords = "Artificial solid electrolyte interphase, Covalent-organic-frameworks, Lithium-ion batteries, Si anode",

author = "Qing Ai and Qiyi Fang and Jia Liang and Xinyu Xu and Tianshu Zhai and Guanhui Gao and Hua Guo and Guifang Han and Lijie Ci and Jun Lou",

year = "2020",

month = jun,

doi = "10.1016/j.nanoen.2020.104657",

language = "English",

volume = "72",

journal = "Nano Energy",

issn = "2211-2855",

publisher = "Elsevier B.V.",

}

Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries. / Ai, Qing (Co-first Author); Fang, Qiyi (Co-first Author); Liang, Jia et al.
In: Nano Energy, Vol. 72, 104657, 06.2020.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries

AU - Ai, Qing

AU - Fang, Qiyi

AU - Liang, Jia

AU - Xu, Xinyu

AU - Zhai, Tianshu

AU - Gao, Guanhui

AU - Guo, Hua

AU - Han, Guifang

AU - Ci, Lijie

AU - Lou, Jun

PY - 2020/6

Y1 - 2020/6

N2 - In this paper, we employ lithium-conducting covalent-organic-framework (COF) as the coating layer for silicon (Si) nanoparticles, which serve as artificial solid electrolyte interphase (SEI) for Si electrode. The COF coating layer reduces the electrolyte decomposition, thus the coulombic efficiency (CE) and cycling stability of the Si electrodes are dramatically improved. Additionally, the superior lithium–ion conductivity of COF can enhance the lithium-ion transportation kinetics of Si electrode. COF coated Si presented a high specific capacity of 1864 mAh g−1 at a high current density of 2000 mA g−1 and high capacity retention of more than 60% after 1000 cycles. © 2020 Published by Elsevier Ltd.

AB - In this paper, we employ lithium-conducting covalent-organic-framework (COF) as the coating layer for silicon (Si) nanoparticles, which serve as artificial solid electrolyte interphase (SEI) for Si electrode. The COF coating layer reduces the electrolyte decomposition, thus the coulombic efficiency (CE) and cycling stability of the Si electrodes are dramatically improved. Additionally, the superior lithium–ion conductivity of COF can enhance the lithium-ion transportation kinetics of Si electrode. COF coated Si presented a high specific capacity of 1864 mAh g−1 at a high current density of 2000 mA g−1 and high capacity retention of more than 60% after 1000 cycles. © 2020 Published by Elsevier Ltd.

KW - Artificial solid electrolyte interphase

KW - Covalent-organic-frameworks

KW - Lithium-ion batteries

KW - Si anode

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85081384928&origin=recordpage

U2 - 10.1016/j.nanoen.2020.104657

DO - 10.1016/j.nanoen.2020.104657

M3 - RGC 21 - Publication in refereed journal

SN - 2211-2855

VL - 72

JO - Nano Energy

JF - Nano Energy

M1 - 104657

ER -

Lithium-conducting covalent-organic-frameworks as artificial solid-electrolyte-interphase on silicon anode for high performance lithium ion batteries

Abstract

Funding

UN SDGs

Research Keywords

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