Lignocellulosic biomass-based pyrolysis: A comprehensive review

K N Yogalakshmi, T Poornima Devi, P Sivashanmugam, S Kavitha, R Yukesh Kannah, Sunita Varjani, S. AdishKumar, Gopalakrishnan Kumar, J Rajesh Banu*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

361 Citations (Scopus)

Abstract

The efficacious application of lignocellulosic biomass for the new valuable chemicals generation curbs the excessive dependency on fossil fuels. Among the various techniques available, pyrolysis has garnered much attention for conversion of lignocellulosic biomass (encompasses cellulose, hemicellulose and lignin components) into product of solid, liquid and gases by thermal decomposition in an efficient manner. Pyrolysis conversion mechanism can be outlined as formation of char, depolymerisation, fragmentation and other secondary reactions. This paper gives a deep insight about the pyrolytic behavior of the lignocellulosic components accompanied by its by-products. Also several parameters such as reaction environment, temperature, residence time and heating rate which has a great impact on the pyrolysis process are also elucidated in a detailed manner. In addition the environmental and economical facet of lignocellulosic biomass pyrolysis for commercialization at industrial scale is critically analyzed. This article also illustrates the prevailing challenges and inhibition in implementing lignocellulosic biomass based pyrolysis with possible solution. © 2021 Elsevier Ltd. All rights reserved.
Original languageEnglish
Article number131824
JournalChemosphere
Volume286
Issue numberPart 2
Online published6 Aug 2021
DOIs
Publication statusPublished - Jan 2022
Externally publishedYes

Research Keywords

  • Bio-oil
  • Biochar
  • Cellulose
  • Hemicellulose
  • Lignin
  • Pyrolysis

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