Abstract
The synthesis of alkenylated-o-carboranesviaphotoalkenylation of iodocarboranes with unactivated alkenes has been achieved. This strategy features a transition metal-free protocol, a light-promoted reaction under mild reaction conditions, broad substrate scope and good functional group tolerance. Control experiments suggest that the reaction may involve the cage C-centered radical species.
| Original language | English |
|---|---|
| Pages (from-to) | 104-110 |
| Journal | Dalton Transactions |
| Volume | 51 |
| Issue number | 1 |
| Online published | 22 Nov 2021 |
| DOIs | |
| Publication status | Published - 7 Jan 2022 |
| Externally published | Yes |
RGC Funding Information
- RGC-funded
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