Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media

Wei-Wei Xiong; Pei-Zhou Li; Tian-Hua Zhou; Alfred Iing Yoong Tok; Rong Xu; Yanli Zhao; Qichun Zhang

doi:10.1021/ic4002169

Author(s)

Wei-Wei Xiong
Pei-Zhou Li
Tian-Hua Zhou
Alfred Iing Yoong Tok
Rong Xu
Yanli Zhao

Detail(s)

Original language	English
Pages (from-to)	4148-4150
Journal / Publication	Inorganic Chemistry
Volume	52
Issue number	8
Online published	4 Apr 2013
Publication status	Published - 15 Apr 2013
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1021/ic4002169 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-84876160356&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(b8fe4ee0-52c0-41dc-91d4-7961d2d51a18).html

Abstract

Herein we report the surfactant-thermal method to prepare two novel one-dimensional mercury selenidostannates, [DBUH]₂[Hg₂Sn₂Se₆(Se₂)] (1) and [DBUH]₂[Hg₂Sn₂Se₇] (2), where DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene, by applying PEG-400 as the reaction medium. It is worth noting that 1 is kinetically stable and can be transformed into thermodynamically stable phase 2 under a longer reaction time. Our strategy "growing crystalline materials in surfactants" could open a new door to preparing novel crystals with diverse structures and interesting properties. © 2013 American Chemical Society.

Citation Format(s)

[ RIS ] [ BibTeX ]

Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media. / Xiong, Wei-Wei; Li, Pei-Zhou; Zhou, Tian-Hua et al.
In: Inorganic Chemistry, Vol. 52, No. 8, 15.04.2013, p. 4148-4150.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Xiong, W-W, Li, P-Z, Zhou, T-H, Tok, AIY, Xu, R, Zhao, Y & Zhang, Q 2013, 'Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media', Inorganic Chemistry, vol. 52, no. 8, pp. 4148-4150. https://doi.org/10.1021/ic4002169

Xiong, W.-W., Li, P.-Z., Zhou, T.-H., Tok, A. I. Y., Xu, R., Zhao, Y., & Zhang, Q. (2013). Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media. Inorganic Chemistry, 52(8), 4148-4150. https://doi.org/10.1021/ic4002169

Xiong WW, Li PZ, Zhou TH, Tok AIY, Xu R, Zhao Y et al. Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media. Inorganic Chemistry. 2013 Apr 15;52(8):4148-4150. Epub 2013 Apr 4. doi: 10.1021/ic4002169

Xiong, Wei-Wei ; Li, Pei-Zhou ; Zhou, Tian-Hua et al. / Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates through Surfactant Media. In: Inorganic Chemistry. 2013 ; Vol. 52, No. 8. pp. 4148-4150.