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Isolation of ruthenium-indolizine complexes: Insight into the metal-induced cycloisomerization of propargylic pyridines

    Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

    Abstract

    A class of ruthenium-indolizine complexes was isolated and structurally characterized, and they represent the first examples of metalated indolizine species. Both experimental and theoretical investigations on the formation of these complexes support a 5-endo-dig cyclization mechanism and discount a vinylidene-5-exo-dig cyclization pathway. © 2013 American Chemical Society.
    Original languageEnglish
    Pages (from-to)3583-3586
    JournalOrganometallics
    Volume32
    Issue number13
    DOIs
    Publication statusPublished - 8 Jul 2013

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