Abstract
We have used Raman spectroscopy to study the behavior of multi-walled boron nitride nanotubes and hexagonal boron nitride crystals under high pressure. While boron nitride nanotubes show an irreversible transformation at about 12 GPa, hexagonal boron nitride exhibits a reversible phase transition at 13 GPa. We also present molecular dynamics simulations which suggest that the irreversibility of the pressure-induced transformation in boron nitride nanotubes is due to the polar nature of the bonds between boron and nitrogen. Copyright © 2007 American Scientific Publishers All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 1810-1814 |
| Journal | Journal of Nanoscience and Nanotechnology |
| Volume | 7 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Jun 2007 |
| Externally published | Yes |
Research Keywords
- Boron nitride nanotube
- High pressure Raman
- Molecular dynamics