Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

Alina Mariana Balu; Carol Sze Ki Lin; Hongli Liu; Yingwei Li; Carolina Vargas; Rafael Luque

doi:10.1016/j.apcata.2013.01.037

Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

Alina Mariana Balu^*
, Carol Sze Ki Lin
, Hongli Liu
, Yingwei Li^*
, Carolina Vargas
, Rafael Luque

^*Corresponding author for this work

School of Energy and Environment

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

40 Citations (Scopus)

Abstract

A highly active Fe containing MIL-101 material has been prepared by using a simple microwave-assisted deposition methodology. The material, characterized by several techniques including N₂ physisorption, XPS and TEM, was found to have a significantly enhanced acidity due to the incorporation of ca. 2 wt.% Fe in the form of hematite Fe₂O₃ phase. Fe/MIL-101 exhibited excelling activities in aqueous phase oxidations of alcohols and alkenes using hydrogen peroxide as green oxidant. © 2013 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	261-266
Journal	Applied Catalysis A: General
Volume	455
DOIs	https://doi.org/10.1016/j.apcata.2013.01.037
Publication status	Published - 30 Mar 2013

Research Keywords

Heterogeneous catalysis
Metal-organic frameworks
Microwave chemistry
Nanoparticles
Oxidation

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title = "Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations",

abstract = "A highly active Fe containing MIL-101 material has been prepared by using a simple microwave-assisted deposition methodology. The material, characterized by several techniques including N2 physisorption, XPS and TEM, was found to have a significantly enhanced acidity due to the incorporation of ca. 2 wt.\% Fe in the form of hematite Fe2O3 phase. Fe/MIL-101 exhibited excelling activities in aqueous phase oxidations of alcohols and alkenes using hydrogen peroxide as green oxidant. {\textcopyright} 2013 Elsevier B.V. All rights reserved.",

keywords = "Heterogeneous catalysis, Metal-organic frameworks, Microwave chemistry, Nanoparticles, Oxidation",

author = "Balu, \{Alina Mariana\} and Lin, \{Carol Sze Ki\} and Hongli Liu and Yingwei Li and Carolina Vargas and Rafael Luque",

year = "2013",

month = mar,

day = "30",

doi = "10.1016/j.apcata.2013.01.037",

language = "English",

volume = "455",

pages = "261--266",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

AU - Balu, Alina Mariana

AU - Lin, Carol Sze Ki

AU - Liu, Hongli

AU - Li, Yingwei

AU - Vargas, Carolina

AU - Luque, Rafael

PY - 2013/3/30

Y1 - 2013/3/30

N2 - A highly active Fe containing MIL-101 material has been prepared by using a simple microwave-assisted deposition methodology. The material, characterized by several techniques including N2 physisorption, XPS and TEM, was found to have a significantly enhanced acidity due to the incorporation of ca. 2 wt.% Fe in the form of hematite Fe2O3 phase. Fe/MIL-101 exhibited excelling activities in aqueous phase oxidations of alcohols and alkenes using hydrogen peroxide as green oxidant. © 2013 Elsevier B.V. All rights reserved.

AB - A highly active Fe containing MIL-101 material has been prepared by using a simple microwave-assisted deposition methodology. The material, characterized by several techniques including N2 physisorption, XPS and TEM, was found to have a significantly enhanced acidity due to the incorporation of ca. 2 wt.% Fe in the form of hematite Fe2O3 phase. Fe/MIL-101 exhibited excelling activities in aqueous phase oxidations of alcohols and alkenes using hydrogen peroxide as green oxidant. © 2013 Elsevier B.V. All rights reserved.

KW - Heterogeneous catalysis

KW - Metal-organic frameworks

KW - Microwave chemistry

KW - Nanoparticles

KW - Oxidation

UR - https://www.scopus.com/pages/publications/84875969529

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84875969529&origin=recordpage

U2 - 10.1016/j.apcata.2013.01.037

DO - 10.1016/j.apcata.2013.01.037

M3 - RGC 21 - Publication in refereed journal

SN - 0926-860X

VL - 455

SP - 261

EP - 266

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

ER -

Iron oxide functionalised MIL-101 materials in aqueous phase selective oxidations

Abstract

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