Investigation of ternary system Pb(Sn,Ti)O3-Pb(Mg1/3Nb2/3)O3 with morphotropic phase boundary compositions

Dawei Wang; Maosheng Cao; Shujun Zhang

doi:10.1016/j.jeurceramsoc.2011.08.038

Investigation of ternary system Pb(Sn,Ti)O₃-Pb(Mg_1/3Nb_2/3)O₃ with morphotropic phase boundary compositions

Dawei Wang, Maosheng Cao, Shujun Zhang

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

44 Citations (Scopus)

Abstract

(1-x)Pb(Sn_1-yTi_y)O₃-xPb(Mg_1/3Nb_2/3)O₃ (x=0.1-0.4, y=0.45-0.65) ternary system was prepared using two-step columbite precursor method. Phase structure of the synthesized ceramics was studied by using X-ray powder diffraction and the morphotropic phase boundary (MPB) curve of the ternary system was confirmed. The isothermal map of Curie temperature (T_C) in the phase diagram was obtained based on the dielectric-temperature measurements. The coercive field E_C and internal bias field E_i were found to increase with increasing PT content, while decrease with increasing PMN content. The optimum properties were achieved in the MPB composition 0.8Pb(Sn_0.45Ti_0.55)O₃-0.2Pb(Mg_1/3Nb_2/3)O₃, with dielectric permittivity e{open}_r, piezoelectric coefficient d₃₃, planar electromechanical coupling k_p, mechanical quality factor Q_m and T_C of being on the order of 3040, 530pC/N, 55.5%, 320 and 190°C, respectively, exhibiting potential usage for high power application. © 2011 Elsevier Ltd.

Original language	English
Pages (from-to)	441-448
Journal	Journal of the European Ceramic Society
Volume	32
Issue number	2
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2011.08.038
Publication status	Published - Feb 2012
Externally published	Yes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to <a href="mailto:[email protected]">[email protected]</a>.

Funding

The authors thank Prof. Thomas R. Shrout for his helpful discussion. Authors from Beijing Institute of Technology acknowledge the National Natural Science Foundation of China under Grant Nos. 50742007 , 50872159 and 50972014 , and the National High Technology Research and Development Program of China under Grant No. 2007AA03Z103 . The author (D.W. Wang) wishes to acknowledge the support from the China Scholarship Council. The work was supported by ONR .

Research Keywords

A. Sintering
C. Dielectric properties
C. Ferroelectric properties
C. Piezoelectric properties
Pb(Sn,Ti)O3-Pb(Mg1/3Nb2/3)O3

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@article{1321d88eda1544f09291d6f05546863f,

title = "Investigation of ternary system Pb(Sn,Ti)O3-Pb(Mg1/3Nb2/3)O3 with morphotropic phase boundary compositions",

abstract = "(1-x)Pb(Sn1-yTiy)O3-xPb(Mg1/3Nb2/3)O3 (x=0.1-0.4, y=0.45-0.65) ternary system was prepared using two-step columbite precursor method. Phase structure of the synthesized ceramics was studied by using X-ray powder diffraction and the morphotropic phase boundary (MPB) curve of the ternary system was confirmed. The isothermal map of Curie temperature (TC) in the phase diagram was obtained based on the dielectric-temperature measurements. The coercive field EC and internal bias field Ei were found to increase with increasing PT content, while decrease with increasing PMN content. The optimum properties were achieved in the MPB composition 0.8Pb(Sn0.45Ti0.55)O3-0.2Pb(Mg1/3Nb2/3)O3, with dielectric permittivity e{open}r, piezoelectric coefficient d33, planar electromechanical coupling kp, mechanical quality factor Qm and TC of being on the order of 3040, 530pC/N, 55.5%, 320 and 190°C, respectively, exhibiting potential usage for high power application. {\textcopyright} 2011 Elsevier Ltd.",

keywords = "A. Sintering, C. Dielectric properties, C. Ferroelectric properties, C. Piezoelectric properties, Pb(Sn,Ti)O3-Pb(Mg1/3Nb2/3)O3",

author = "Dawei Wang and Maosheng Cao and Shujun Zhang",

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TY - JOUR

T1 - Investigation of ternary system Pb(Sn,Ti)O3-Pb(Mg1/3Nb2/3)O3 with morphotropic phase boundary compositions

AU - Wang, Dawei

AU - Cao, Maosheng

AU - Zhang, Shujun

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to <a href="mailto:[email protected]">[email protected]</a>.

PY - 2012/2

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N2 - (1-x)Pb(Sn1-yTiy)O3-xPb(Mg1/3Nb2/3)O3 (x=0.1-0.4, y=0.45-0.65) ternary system was prepared using two-step columbite precursor method. Phase structure of the synthesized ceramics was studied by using X-ray powder diffraction and the morphotropic phase boundary (MPB) curve of the ternary system was confirmed. The isothermal map of Curie temperature (TC) in the phase diagram was obtained based on the dielectric-temperature measurements. The coercive field EC and internal bias field Ei were found to increase with increasing PT content, while decrease with increasing PMN content. The optimum properties were achieved in the MPB composition 0.8Pb(Sn0.45Ti0.55)O3-0.2Pb(Mg1/3Nb2/3)O3, with dielectric permittivity e{open}r, piezoelectric coefficient d33, planar electromechanical coupling kp, mechanical quality factor Qm and TC of being on the order of 3040, 530pC/N, 55.5%, 320 and 190°C, respectively, exhibiting potential usage for high power application. © 2011 Elsevier Ltd.

AB - (1-x)Pb(Sn1-yTiy)O3-xPb(Mg1/3Nb2/3)O3 (x=0.1-0.4, y=0.45-0.65) ternary system was prepared using two-step columbite precursor method. Phase structure of the synthesized ceramics was studied by using X-ray powder diffraction and the morphotropic phase boundary (MPB) curve of the ternary system was confirmed. The isothermal map of Curie temperature (TC) in the phase diagram was obtained based on the dielectric-temperature measurements. The coercive field EC and internal bias field Ei were found to increase with increasing PT content, while decrease with increasing PMN content. The optimum properties were achieved in the MPB composition 0.8Pb(Sn0.45Ti0.55)O3-0.2Pb(Mg1/3Nb2/3)O3, with dielectric permittivity e{open}r, piezoelectric coefficient d33, planar electromechanical coupling kp, mechanical quality factor Qm and TC of being on the order of 3040, 530pC/N, 55.5%, 320 and 190°C, respectively, exhibiting potential usage for high power application. © 2011 Elsevier Ltd.

KW - A. Sintering

KW - C. Dielectric properties

KW - C. Ferroelectric properties

KW - C. Piezoelectric properties

KW - Pb(Sn,Ti)O3-Pb(Mg1/3Nb2/3)O3

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U2 - 10.1016/j.jeurceramsoc.2011.08.038

DO - 10.1016/j.jeurceramsoc.2011.08.038

M3 - RGC 21 - Publication in refereed journal

SN - 0955-2219

VL - 32

SP - 441

EP - 448

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

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