Intermetal Oxo Transfer: Isomerization of Tungsten‒Rhenium Carbonyl Complexes Containing Oxo and Acetylide Ligands

Nien-Sheng Lai; Wen-Cheng Tu; Yun Chi; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1021/om00024a002

Intermetal Oxo Transfer: Isomerization of Tungsten‒Rhenium Carbonyl Complexes Containing Oxo and Acetylide Ligands

Nien-Sheng Lai, Wen-Cheng Tu, Yun Chi, Shie-Ming Peng, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

19 Citations (Scopus)

Abstract

The heterometallic oxo–acetylide complex Cp*Re(O)(µ-C₂Ph)W(CO)₂Cp (1), possessing an oxo ligand bound to the Re atom, was prepared by treatment of [Cp*Re(O)(µ-O)]₂ with the acetylide complex CpW(CO)₃(CCPh) in refluxing toluene. Further thermolysis of 1 afforded the isomeric complex Cp*Re(CO)₂(µ-C₂Ph)W(O)Cp (2), showing an intermetal transfer of oxygen atom from Re to W atoms.

Original language	English
Pages (from-to)	4652-4654
Journal	Organometallics
Volume	13
Issue number	12
DOIs	https://doi.org/10.1021/om00024a002
Publication status	Published - 1 Dec 1994
Externally published	Yes

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title = "Intermetal Oxo Transfer: Isomerization of Tungsten‒Rhenium Carbonyl Complexes Containing Oxo and Acetylide Ligands",

abstract = "The heterometallic oxo–acetylide complex Cp*Re(O)(µ-C2Ph)W(CO)2Cp (1), possessing an oxo ligand bound to the Re atom, was prepared by treatment of [Cp*Re(O)(µ-O)]2 with the acetylide complex CpW(CO)3(CCPh) in refluxing toluene. Further thermolysis of 1 afforded the isomeric complex Cp*Re(CO)2(µ-C2Ph)W(O)Cp (2), showing an intermetal transfer of oxygen atom from Re to W atoms. ",

author = "Nien-Sheng Lai and Wen-Cheng Tu and Yun Chi and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1994",

month = dec,

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doi = "10.1021/om00024a002",

language = "English",

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journal = "Organometallics",

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TY - JOUR

T1 - Intermetal Oxo Transfer

T2 - Isomerization of Tungsten‒Rhenium Carbonyl Complexes Containing Oxo and Acetylide Ligands

AU - Lai, Nien-Sheng

AU - Tu, Wen-Cheng

AU - Chi, Yun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The heterometallic oxo–acetylide complex Cp*Re(O)(µ-C2Ph)W(CO)2Cp (1), possessing an oxo ligand bound to the Re atom, was prepared by treatment of [Cp*Re(O)(µ-O)]2 with the acetylide complex CpW(CO)3(CCPh) in refluxing toluene. Further thermolysis of 1 afforded the isomeric complex Cp*Re(CO)2(µ-C2Ph)W(O)Cp (2), showing an intermetal transfer of oxygen atom from Re to W atoms.

AB - The heterometallic oxo–acetylide complex Cp*Re(O)(µ-C2Ph)W(CO)2Cp (1), possessing an oxo ligand bound to the Re atom, was prepared by treatment of [Cp*Re(O)(µ-O)]2 with the acetylide complex CpW(CO)3(CCPh) in refluxing toluene. Further thermolysis of 1 afforded the isomeric complex Cp*Re(CO)2(µ-C2Ph)W(O)Cp (2), showing an intermetal transfer of oxygen atom from Re to W atoms.

UR - http://www.scopus.com/inward/record.url?scp=0001287629&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0001287629&origin=recordpage

U2 - 10.1021/om00024a002

DO - 10.1021/om00024a002

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 13

SP - 4652

EP - 4654

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Intermetal Oxo Transfer: Isomerization of Tungsten‒Rhenium Carbonyl Complexes Containing Oxo and Acetylide Ligands

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