Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications

Irum Shaheen; Ijaz Ali; Faiza Bibi; Abdul Hanan; Muhammad Ahmad; Ishtihar Hussain; Muhammad Sufyan Javed; Syed Shoaib Ahmad Shah; Karim Khan; Muhammad Bilal Hanif; Martin Motola; P. Rosaiah; Saikh Mohammad Wabaidur; Waqas Ul Arifeen; Iftikhar Hussain

doi:10.1016/j.ceramint.2023.12.394

Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications

Irum Shaheen, Ijaz Ali, Faiza Bibi, Abdul Hanan, Muhammad Ahmad, Ishtihar Hussain, Muhammad Sufyan Javed, Syed Shoaib Ahmad Shah, Karim Khan, Muhammad Bilal Hanif, Martin Motola, P. Rosaiah, Saikh Mohammad Wabaidur, Waqas Ul Arifeen^*, Iftikhar Hussain^*

^*Corresponding author for this work

Department of Mechanical Engineering

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

26 Citations (Scopus)

Abstract

The performance of an electrochemical energy storage device highly depends on the electrode material. Currently, metal oxalates are evolving as low-cost and stable electrode materials for batteries and supercapacitors. Herein, mixed metal oxalate (Ni_xCo_1-xC₂O₄/NF) based binder-free electrode was fabricated. The nickel foam contributed not only as a substrate but also as a nickel source. The Ni_xCo_1-xC₂O₄/NF confirmed the crystalline phase through X-ray diffraction spectroscopy (XRD). Scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM) confirmed the integrated 1D/2D-like morphology of Ni_xCo_1-xC₂O₄/NF. The electrochemical results reveled the Ni_xCo_1-xC₂O₄/NF electrode exhibit battery behavior with capacity retention of 86.58 % and possessed the highest specific capacity of 470.012 C g⁻¹ at 1 A g^-1. Hence, the nickel inclusion during the synthesis has further enhanced the overall properties and performance of the Ni_xCo_1-xC₂O₄/NF electrode. © 2023 Elsevier Ltd and Techna Group S.r.l.

Original language	English
Pages (from-to)	10789-10796
Number of pages	8
Journal	Ceramics International
Volume	50
Issue number	7
Online published	28 Dec 2023
DOIs	https://doi.org/10.1016/j.ceramint.2023.12.394
Publication status	Published - 1 Apr 2024

Funding

This work was supported by the Hong Kong Research Grants Council (project number CityU 11218420). Authors are grateful to the Researchers Supporting Project Number (RSP2024R448), King Saud University, Riyadh, Saudi Arabia.

Research Keywords

Capacity
Electrode
Mixed metal oxalate
Nickel salt-free

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Shaheen, I., Ali, I., Bibi, F., Hanan, A., Ahmad, M., Hussain, I., Javed, M. S., Ahmad Shah, S. S., Khan, K., Hanif, M. B., Motola, M., Rosaiah, P., Wabaidur, S. M., Arifeen, W. U., & Hussain, I. (2024). Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications. Ceramics International, 50(7), 10789-10796. https://doi.org/10.1016/j.ceramint.2023.12.394

@article{8f328b4f54eb4550a5e000e8d0b4f0af,

title = "Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications",

abstract = "The performance of an electrochemical energy storage device highly depends on the electrode material. Currently, metal oxalates are evolving as low-cost and stable electrode materials for batteries and supercapacitors. Herein, mixed metal oxalate (NixCo1-xC2O4/NF) based binder-free electrode was fabricated. The nickel foam contributed not only as a substrate but also as a nickel source. The NixCo1-xC2O4/NF confirmed the crystalline phase through X-ray diffraction spectroscopy (XRD). Scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM) confirmed the integrated 1D/2D-like morphology of NixCo1-xC2O4/NF. The electrochemical results reveled the NixCo1-xC2O4/NF electrode exhibit battery behavior with capacity retention of 86.58 % and possessed the highest specific capacity of 470.012 C g−1 at 1 A g-1. Hence, the nickel inclusion during the synthesis has further enhanced the overall properties and performance of the NixCo1-xC2O4/NF electrode. {\textcopyright} 2023 Elsevier Ltd and Techna Group S.r.l.",

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author = "Irum Shaheen and Ijaz Ali and Faiza Bibi and Abdul Hanan and Muhammad Ahmad and Ishtihar Hussain and Javed, {Muhammad Sufyan} and {Ahmad Shah}, {Syed Shoaib} and Karim Khan and Hanif, {Muhammad Bilal} and Martin Motola and P. Rosaiah and Wabaidur, {Saikh Mohammad} and Arifeen, {Waqas Ul} and Iftikhar Hussain",

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Shaheen, I, Ali, I, Bibi, F, Hanan, A, Ahmad, M, Hussain, I, Javed, MS, Ahmad Shah, SS, Khan, K, Hanif, MB, Motola, M, Rosaiah, P, Wabaidur, SM, Arifeen, WU & Hussain, I 2024, 'Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications', Ceramics International, vol. 50, no. 7, pp. 10789-10796. https://doi.org/10.1016/j.ceramint.2023.12.394

TY - JOUR

T1 - Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications

AU - Shaheen, Irum

AU - Ali, Ijaz

AU - Bibi, Faiza

AU - Hanan, Abdul

AU - Ahmad, Muhammad

AU - Hussain, Ishtihar

AU - Javed, Muhammad Sufyan

AU - Ahmad Shah, Syed Shoaib

AU - Khan, Karim

AU - Hanif, Muhammad Bilal

AU - Motola, Martin

AU - Rosaiah, P.

AU - Wabaidur, Saikh Mohammad

AU - Arifeen, Waqas Ul

AU - Hussain, Iftikhar

PY - 2024/4/1

Y1 - 2024/4/1

N2 - The performance of an electrochemical energy storage device highly depends on the electrode material. Currently, metal oxalates are evolving as low-cost and stable electrode materials for batteries and supercapacitors. Herein, mixed metal oxalate (NixCo1-xC2O4/NF) based binder-free electrode was fabricated. The nickel foam contributed not only as a substrate but also as a nickel source. The NixCo1-xC2O4/NF confirmed the crystalline phase through X-ray diffraction spectroscopy (XRD). Scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM) confirmed the integrated 1D/2D-like morphology of NixCo1-xC2O4/NF. The electrochemical results reveled the NixCo1-xC2O4/NF electrode exhibit battery behavior with capacity retention of 86.58 % and possessed the highest specific capacity of 470.012 C g−1 at 1 A g-1. Hence, the nickel inclusion during the synthesis has further enhanced the overall properties and performance of the NixCo1-xC2O4/NF electrode. © 2023 Elsevier Ltd and Techna Group S.r.l.

AB - The performance of an electrochemical energy storage device highly depends on the electrode material. Currently, metal oxalates are evolving as low-cost and stable electrode materials for batteries and supercapacitors. Herein, mixed metal oxalate (NixCo1-xC2O4/NF) based binder-free electrode was fabricated. The nickel foam contributed not only as a substrate but also as a nickel source. The NixCo1-xC2O4/NF confirmed the crystalline phase through X-ray diffraction spectroscopy (XRD). Scanning electron microscopy (SEM) and transmission electron spectroscopy (TEM) confirmed the integrated 1D/2D-like morphology of NixCo1-xC2O4/NF. The electrochemical results reveled the NixCo1-xC2O4/NF electrode exhibit battery behavior with capacity retention of 86.58 % and possessed the highest specific capacity of 470.012 C g−1 at 1 A g-1. Hence, the nickel inclusion during the synthesis has further enhanced the overall properties and performance of the NixCo1-xC2O4/NF electrode. © 2023 Elsevier Ltd and Techna Group S.r.l.

KW - Capacity

KW - Electrode

KW - Mixed metal oxalate

KW - Nickel salt-free

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U2 - 10.1016/j.ceramint.2023.12.394

DO - 10.1016/j.ceramint.2023.12.394

M3 - RGC 21 - Publication in refereed journal

SN - 0272-8842

VL - 50

SP - 10789

EP - 10796

JO - Ceramics International

JF - Ceramics International

IS - 7

ER -

Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications

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GRF: Fabrication, Energetic and Combustion Properties of Energetic Microchip Based on In Situ Synthesized Energetic Coordination Polymer and Aluminum

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Integrating 1D/2D nanostructure based on Ni–Co-oxalate for energy storage applications

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Research Keywords

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GRF: Fabrication, Energetic and Combustion Properties of Energetic Microchip Based on In Situ Synthesized Energetic Coordination Polymer and Aluminum

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