Inorganic-organic hybridization induced uniaxial zero thermal expansion in MC4O4 (M = Ba, Pb)

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Author(s)

  • Zhanning Liu
  • Kun Lin
  • Kenichi Kato
  • Yili Cao
  • Jinxia Deng
  • Jun Chen
  • Xianran Xing

Detail(s)

Original languageEnglish
Pages (from-to)4107-4110
Journal / PublicationChemical Communications
Volume55
Issue number28
Publication statusPublished - 11 Apr 2019
Externally publishedYes

Abstract

We report two inorganic-organic hybrid materials with pillar-layered architectures, BaC4O4 and PbC4O4, which show uniaxial zero thermal expansion (ZTE) along the hybrid direction over a wide temperature range. The local structure and lattice dynamic investigations reveal that the ZTE derives from the cooperation of the NTE of the inorganic Ba-O (or Pb-O) layer and the PTE of the squarate pillar.

Bibliographic Note

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Citation Format(s)

Inorganic-organic hybridization induced uniaxial zero thermal expansion in MC4O4 (M = Ba, Pb). / Liu, Zhanning; Lin, Kun; Ren, Yang et al.
In: Chemical Communications, Vol. 55, No. 28, 11.04.2019, p. 4107-4110.

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review