In situ study of single aqueous droplet solidification of ceramic precursors used for spray pyrolysis

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalNot applicablepeer-review

30 Scopus Citations
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Original languageEnglish
Pages (from-to)646-648
Journal / PublicationJournal of the American Ceramic Society
Volume81
Issue number3
Publication statusPublished - Mar 1998
Externally publishedYes

Abstract

The electrodynamic balance (EDB) is demonstrated to be useful for the in situ study of aqueous droplet solidification. We have used an EDB to study the solidification of solution droplets used for ceramic powder synthesis by spray pyrolysis. The mass change and the elastic light scattering of the drying 20 μm solution droplets were monitored. We found that aqueous MgCl2 droplets crystallize but Mg-(COOCH3)2, MgSO4, ZrO(OH)Cl, and Zr(COOCH3)4 droplets appear to form gels at high concentrations. As a result of the gel formation, the rate of loss of water from the droplets can be reduced by approximately 150 times and drying is limited by solute diffusion in the gel.

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