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In situ resistivity measurement of cobalt silicide formation

  • G. Ottaviani
  • , K. N. Tu
  • , P. Psaras
  • , C. Nobili

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

In situ resistivity measurements have been utilized to study the reaction and silicide formation between cobalt and amorphous silicon thin films from room temperature to 800 °C. In conjunction, structure and composition changes were analyzed by x-ray diffraction and Rutherford backscattering spectrometry. Formation of Co2Si, CoSi, and CoSi2 were observed. Interfacial reaction to form Co2Si occurs at approximately 400 °C. In bilayers of excess silicon, CoSi forms at approximately 520 °C and, if free silicon is still present, CoSi2 forms at about 550 °C. In the case of excess cobalt, Co2Si forms first and is followed by a cobalt-rich solid solution. Co3Si silicide was not observed.
Original languageEnglish
Pages (from-to)2290-2294
JournalJournal of Applied Physics
Volume62
Issue number6
DOIs
Publication statusPublished - 1987
Externally publishedYes

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