Improving stability against desolvation and mercury removal performance of Zr(IV)-carboxylate frameworks by using bulky sulfur functions

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

11 Scopus Citations
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Author(s)

  • Yonghe He
  • Zhifeng Hao
  • Jian Huang
  • Lei Wang
  • Matthias Zeller
  • Jun He

Related Research Unit(s)

Detail(s)

Original languageEnglish
Pages (from-to)1648-1654
Journal / PublicationJournal of Materials Chemistry A
Volume6
Issue number4
Online published18 Dec 2017
Publication statusPublished - 28 Jan 2018

Abstract

Like killing two birds with one stone, we here utilize sulfur functionalization to simultaneously mitigate the persistent instability issue of the famous Zr(iv)-based metal-organic frameworks (MOFs) and impart effective metal uptake capabilities for broader potential applications. Thioether side groups can be conveniently designed to have various sizes and configurations, and offer unique advantages for functionalizing and stabilizing highly porous frameworks. Sulfuration as such on Zr(iv)-based frameworks is meaningful, because these MOF materials, in spite of their improved stability when protected by solvents, often degrade fast upon exposure to air, therefore limiting applications that involve gas-solid interfaces. For better practical impact, here we install sulfur side chains, e.g., tris(methylthiomethyl)methyl, that are conveniently derived from inexpensive pentaerythrityl compounds. One notable advance achieved pertains to a UiO-68-type porous solid (i.e., based on terphenyl dicarboxyl linkers) featuring long-term stability in direct exposure to air, while maintaining significant mercury uptake capability from water and organic solutions. Also discovered is a cubic NU-1100-type net that offers more efficient mercury removal capability (with regards to the adsorption capacity as well as binding strength as measured from the distribution coefficient Kd) than other thioether-equipped MOF materials.

Citation Format(s)

Improving stability against desolvation and mercury removal performance of Zr(IV)-carboxylate frameworks by using bulky sulfur functions. / He, Yonghe; Hou, Yun-Long; Wong, Yan-Lung; Xiao, Ran; Li, Mu-Qing; Hao, Zhifeng; Huang, Jian; Wang, Lei; Zeller, Matthias; He, Jun; Xu, Zhengtao.

In: Journal of Materials Chemistry A, Vol. 6, No. 4, 28.01.2018, p. 1648-1654.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal