TY - GEN
T1 - Hydrogen production from deliquescence of ammonia borane
AU - Chou, Chang-Chen
AU - Liu, Cheng-Hong
AU - Chen, Bing-Hung
AU - Lee, Duu-Jong
N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].
PY - 2011
Y1 - 2011
N2 - Chemical hydride is one of the most potential hydrogen storage materials which can effectively increase hydrogen storage capacity. To meet the new goal of U.S. department of energy (DoE), 4.5wt% and 5.5 wt% of gravimetric hydrogen density capacity by 2010 and 2015, respectively, ammonia borane (AB) is an attractive material due to high intrinsic hydrogen density (i.e. 19.6 wt%). Such a high intrinsic hydrogen density increases the possibility to apply to be the on-board power source of vehicle system, not only for 3C electric product. In this study, hydrogen evolution from hydrolysis of ammonia borane in limiting water conditions is studied. The solid composite of ammonia borane hydrogen fuel is synthesized with pulverized catalyst through the high energy ball milling process. Various parameters such as the amount of water dosage, temperature, loading of catalysts, on hydrogen production characteristics will be discussed. Kinetic behavior of the hydrolysis reaction in such limiting water supply conditions will also be investigated. Based on experimental outcomes, optimal conditions on hydrogen production from this hydrogen storage system will be proposed.
AB - Chemical hydride is one of the most potential hydrogen storage materials which can effectively increase hydrogen storage capacity. To meet the new goal of U.S. department of energy (DoE), 4.5wt% and 5.5 wt% of gravimetric hydrogen density capacity by 2010 and 2015, respectively, ammonia borane (AB) is an attractive material due to high intrinsic hydrogen density (i.e. 19.6 wt%). Such a high intrinsic hydrogen density increases the possibility to apply to be the on-board power source of vehicle system, not only for 3C electric product. In this study, hydrogen evolution from hydrolysis of ammonia borane in limiting water conditions is studied. The solid composite of ammonia borane hydrogen fuel is synthesized with pulverized catalyst through the high energy ball milling process. Various parameters such as the amount of water dosage, temperature, loading of catalysts, on hydrogen production characteristics will be discussed. Kinetic behavior of the hydrolysis reaction in such limiting water supply conditions will also be investigated. Based on experimental outcomes, optimal conditions on hydrogen production from this hydrogen storage system will be proposed.
UR - http://www.scopus.com/inward/record.url?scp=84863145008&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84863145008&origin=recordpage
M3 - RGC 32 - Refereed conference paper (with host publication)
SN - 9780816910700
T3 - 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings
BT - 11AIChE - 2011 AIChE Annual Meeting, Conference Proceedings
T2 - 2011 AIChE Annual Meeting, 11AIChE
Y2 - 16 October 2011 through 21 October 2011
ER -