Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Overview

57 Scopus Citations

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Author(s)

Derek Yiren Ong
Ciputra Tejo
Kai Xu
Hajime Hirao
Shunsuke Chiba

Detail(s)

Original language	English
Pages (from-to)	1840-1844
Journal / Publication	Angewandte Chemie - International Edition
Volume	56
Issue number	7
Publication status	Published - 6 Feb 2017
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/anie.201611495 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-85010886912&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(180362ba-de80-40f7-b960-c15e6afce15f).html

Abstract

A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.

Research Area(s)

DFT calculations, haloarenes, hydrodehalogenation, reduction, sodium hydride

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Publication fingerprints text

Sodium Iodide Medicine & Life Sciences

Iodides Medicine & Life Sciences

Lithium Medicine & Life Sciences

Hydrides Engineering & Materials S...

Sodium Medicine & Life Sciences

Substitution reacti... Engineering & Materials S...

Composite materials Engineering & Materials S...

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Citation Format(s)

[ RIS ] [ BibTeX ]

Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite. / Ong, Derek Yiren; Tejo, Ciputra; Xu, Kai et al.

In: Angewandte Chemie - International Edition, Vol. 56, No. 7, 06.02.2017, p. 1840-1844.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Ong, DY, Tejo, C, Xu, K, Hirao, H & Chiba, S 2017, 'Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite', Angewandte Chemie - International Edition, vol. 56, no. 7, pp. 1840-1844. https://doi.org/10.1002/anie.201611495

Ong, D. Y., Tejo, C., Xu, K., Hirao, H., & Chiba, S. (2017). Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite. Angewandte Chemie - International Edition, 56(7), 1840-1844. https://doi.org/10.1002/anie.201611495

Ong DY, Tejo C, Xu K, Hirao H, Chiba S. Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite. Angewandte Chemie - International Edition. 2017 Feb 6;56(7):1840-1844. doi: 10.1002/anie.201611495

Ong, Derek Yiren ; Tejo, Ciputra ; Xu, Kai et al. / Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite. In: Angewandte Chemie - International Edition. 2017 ; Vol. 56, No. 7. pp. 1840-1844.