How does mass transfer influence electrochemical carbon dioxide reduction reaction? A case study of Ni molecular catalyst supported on carbon

Chang Guo; Song Liu; Zhiwen Chen; Bingyu Li; Lixin Chen; Chandra Veer Singh; Bin Liu; Qing Mao

doi:10.1039/d0cc07466g

How does mass transfer influence electrochemical carbon dioxide reduction reaction? A case study of Ni molecular catalyst supported on carbon

Chang Guo, Song Liu, Zhiwen Chen, Bingyu Li, Lixin Chen, Chandra Veer Singh^*, Bin Liu^*, Qing Mao^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

22 Citations (Scopus)

Abstract

A series of heterogeneous molecular catalysts by immobilizing nickel(ii) phthalocyanine (NiPc) onto different carbon supports were constructed to study the influence of the catalyst's microstructure on the performance of electrochemical carbon dioxide reduction reaction (CO₂RR). The microporous structure of the electrocatalysts could influence CO₂transfer and therefore change the CO₂concentration at the surface of the catalyst, which singnificantly impacted the CO₂RR performance. © The Royal Society of Chemistry 2021.

Original language	English
Pages (from-to)	1384-1387
Journal	Chemical Communications
Volume	57
Issue number	11
Online published	8 Jan 2021
DOIs	https://doi.org/10.1039/d0cc07466g
Publication status	Published - 7 Feb 2021
Externally published	Yes

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title = "How does mass transfer influence electrochemical carbon dioxide reduction reaction? A case study of Ni molecular catalyst supported on carbon",

abstract = "A series of heterogeneous molecular catalysts by immobilizing nickel(ii) phthalocyanine (NiPc) onto different carbon supports were constructed to study the influence of the catalyst's microstructure on the performance of electrochemical carbon dioxide reduction reaction (CO2RR). The microporous structure of the electrocatalysts could influence CO2transfer and therefore change the CO2concentration at the surface of the catalyst, which singnificantly impacted the CO2RR performance. {\textcopyright} The Royal Society of Chemistry 2021.",

author = "Chang Guo and Song Liu and Zhiwen Chen and Bingyu Li and Lixin Chen and Singh, {Chandra Veer} and Bin Liu and Qing Mao",

year = "2021",

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language = "English",

volume = "57",

pages = "1384--1387",

journal = "Chemical Communications",

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TY - JOUR

T1 - How does mass transfer influence electrochemical carbon dioxide reduction reaction? A case study of Ni molecular catalyst supported on carbon

AU - Guo, Chang

AU - Liu, Song

AU - Chen, Zhiwen

AU - Li, Bingyu

AU - Chen, Lixin

AU - Singh, Chandra Veer

AU - Liu, Bin

AU - Mao, Qing

PY - 2021/2/7

Y1 - 2021/2/7

N2 - A series of heterogeneous molecular catalysts by immobilizing nickel(ii) phthalocyanine (NiPc) onto different carbon supports were constructed to study the influence of the catalyst's microstructure on the performance of electrochemical carbon dioxide reduction reaction (CO2RR). The microporous structure of the electrocatalysts could influence CO2transfer and therefore change the CO2concentration at the surface of the catalyst, which singnificantly impacted the CO2RR performance. © The Royal Society of Chemistry 2021.

AB - A series of heterogeneous molecular catalysts by immobilizing nickel(ii) phthalocyanine (NiPc) onto different carbon supports were constructed to study the influence of the catalyst's microstructure on the performance of electrochemical carbon dioxide reduction reaction (CO2RR). The microporous structure of the electrocatalysts could influence CO2transfer and therefore change the CO2concentration at the surface of the catalyst, which singnificantly impacted the CO2RR performance. © The Royal Society of Chemistry 2021.

UR - http://www.scopus.com/inward/record.url?scp=85101094542&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85101094542&origin=recordpage

U2 - 10.1039/d0cc07466g

DO - 10.1039/d0cc07466g

M3 - RGC 21 - Publication in refereed journal

C2 - 33438691

SN - 1359-7345

VL - 57

SP - 1384

EP - 1387

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

How does mass transfer influence electrochemical carbon dioxide reduction reaction? A case study of Ni molecular catalyst supported on carbon

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