Homoleptic copper(I) phenylselenolate polymer as a single-source precursor for Cu2Se nanocrystals. Structure, photoluminescence and application in field-effect transistor
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 515-518 |
Journal / Publication | Chemical Science |
Volume | 1 |
Issue number | 4 |
Publication status | Published - 1 Oct 2010 |
Link(s)
Abstract
We present the one-dimensional polymeric structures of [Cu(SePh)] ∞ 1 and [Cu(SeMe)]∞ 2 that were solved by using powder X-ray diffraction data. Using a field-effect transistor (FET) set-up, the hole mobility of complex 1 was found to be 4 × 10-2 cm2 V-1 s-1, comparable to that of regioregular poly-(3-hexylthiophene) (P3HT). Phase-pure orthorhombic and cubic Cu2Se were synthesized from 1 as a single precursor under vacuum and inert atmosphere, respectively. © 2010 The Royal Society of Chemistry.
Citation Format(s)
Homoleptic copper(I) phenylselenolate polymer as a single-source precursor for Cu2Se nanocrystals. Structure, photoluminescence and application in field-effect transistor. / Low, Kam-Hung; Li, Cheng-Hui; Roy, Vellaisamy A. L. et al.
In: Chemical Science, Vol. 1, No. 4, 01.10.2010, p. 515-518.
In: Chemical Science, Vol. 1, No. 4, 01.10.2010, p. 515-518.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review