Highly Selective Self-Powered Organic-Inorganic Hybrid Heterojunction of a Halide Perovskite and InGaZnO NO₂ Sensor

Self-powered sensors can lead to disruptive advances in self-sustainable sensing systems that are imperative for evolving human lifestyles. For the first time, we demonstrate the fabrication of a heterojunction sensor using p-type hybrid-halide perovskites (CH₃NH₃PbBr₃) and an n-type semiconducting metal oxide thin film [InGaZnO (IGZO)] for the detection of NO₂ gas and power generation. Combining the excellent photoelectric properties of perovskites and the remarkable gas-sensing properties of IGZO at room temperature, the devised sensors generate open-circuit voltage and modulate according to the ambient NO₂ concentration. The major challenge in devising self-powered gas sensors is to attain harvesting capability and selectivity simultaneously, owing to perovskites reactivity in the presence of oxygen and humidity. In this work, we developed a novel approach and fabricated a heterojunction sensor using parylene-c as an additional layer to curb the cross-sensitivity and to enhance the selectivity of the sensor. Even under the low concentrations of NO₂, the developed sensor exhibits remarkable sensitivity, selectivity, and repeatability. The devices are sensitive and robust even under extreme humidity conditions (80% R_H) and synthetic air. The devised sensor configuration is one way to eliminate the cross-sensitivity issue of the perovskite-based devices and serves as a reference for the development of self-powered sensors.